Question

What are the physicochemical technical parameters of Emulsifier 600 (tristyrylphenol polyoxyethylene ether)?

Answer

Physicochemical Technical Parameters of Emulsifier 600 (Tristyrylphenol Polyoxyethylene Ether) Cover Various Indicators Such as Appearance, HLB Value, Cloud Point, Viscosity, Density, and pH Value, with Detailed Data Provided Below.

Detailed Description

The chemical name of Emulsifier 600 is polyoxyethylene tristyrylphenol ether, with CAS number 99734-09-5. The molecular formula can be expressed as C₆H₅C(C₈H₈)₃O(C₂H₄O)ₙH, where the EO addition number n≈20, and the average molecular weight is approximately 1300. This product is a nonionic surfactant, appearing as a light yellow to brownish yellow viscous liquid. Its viscosity increases as temperature decreases, it is easily soluble in water, and has hygroscopicity.

Among its core performance parameters, the HLB value (hydrophilic-lipophilic balance) is 13.5, and the cloud point is ≥90°C (1% aqueous solution), indicating strong hydrophilicity, suitable for O/W emulsification systems. The surface tension of a 1% aqueous solution at 25°C ranges from 30 to 35 mN/m, and the critical micelle concentration (CMC) is approximately 1×10⁻⁴ mol/L, demonstrating excellent surface activity.

The product has an active content of ≥99.0%, moisture ≤0.5%, acid value ≤0.5 mgKOH/g, saponification value ≤2.0 mgKOH/g, iodine value ≤1 gI₂/100g, and unsaturation ≤0.01 mol/kg, indicating high purity. Under normal temperature conditions, the product is chemically stable, but contact with strong oxidizing agents should be avoided.

Technical Parameters

Parameter ItemSpecification/ValueRemarks
Ion TypeNonionic
AppearanceLight yellow to brownish yellow viscous liquidFlowable, viscosity increases as temperature decreases
Active Content≥99.0%
HLB Value13.5Strong hydrophilicity, suitable for O/W emulsions
Cloud Point (1% Aqueous Solution)≥90°C
pH Value (1% Aqueous Solution)5.0~7.0
Density (25°C)1.08~1.12 g/cm³
Kinematic Viscosity (40°C)200~500 mm²/s
Low Shear Viscosity200~500 mPa·s
Refractive Index (20°C)1.490~1.495
Surface Tension (1% Aqueous Solution, 25°C)30~35 mN/m
Critical Micelle Concentration (CMC)Approximately 1×10⁻⁴ mol/L
Acid Value≤0.5 mgKOH/g
Saponification Value≤2.0 mgKOH/g
Iodine Value≤1 gI₂/100g
Unsaturation≤0.01 mol/kg
Hydroxyl ValueVaries with EO numberNo fixed value data available
Moisture≤0.5%
Flash Point>150°C
SolubilityEasily soluble in water
Foam CharacteristicsLow foam
Penetrating PowerGood
Alkali ResistanceAlkali resistant
Heavy Metals (as Pb)≤20 mg/kg
Arsenic (As)≤3 mg/kg
Packaging Specifications50kg plastic drum / 200kg plastic drum / IBC tote

Application Recommendations

Given that Emulsifier 600 has an HLB value of 13.5, a cloud point ≥90°C, and is easily soluble in water, this product is very suitable as a primary emulsifier or co-emulsifier for O/W emulsions. In pesticide formulations (such as emulsifiable concentrates, aqueous emulsions, microemulsions), its excellent dispersibility and emulsion stability can significantly enhance efficacy; in textile printing and dyeing, as a leveling agent, it can improve dye migration effects through good penetrating power; in industrial cleaning formulations, its low foam and easy water solubility characteristics can be utilized to formulate efficient degreasing cleaners.

It is recommended to adjust the dosage in the formulation according to the specific system. When used as the main emulsifier, the amount is typically between 2% and 8%. Compounding with anionic surfactants (such as Emulsifier 500, calcium salts, etc.) can achieve better synergistic effects.

Precautions

  • This product is hygroscopic. Use it as soon as possible after opening, and keep the container tightly closed during storage.
  • The recommended storage temperature is 5~35°C, avoiding extreme temperatures and direct sunlight.
  • Wear chemical protective gloves and goggles during operation to avoid skin and eye contact. For specific safety information, please refer to the Safety Data Sheet (SDS).