Question

Usage of G-18 Glycereth-18, Polyoxyethylene Glyceryl Ether?

Answer

The usage of G-18 Glycereth-18 varies by application area, typically added directly or pre-diluted into the formulation system. The recommended dosage range is 0.5% to 10% (w/w), and specific optimization adjustments should be made based on the system type and process requirements.

Detailed Description

G-18 Glycereth-18 (INCI name: Glycereth-18, CAS number: 31694-55-0) is a nonionic surfactant with a high HLB value (18). It appears as a colorless to light yellow transparent liquid, easily soluble in water, with a cloud point above 100°C and excellent chemical stability (stable within pH 3~12). Its molecular structure features a glycerol backbone with approximately 18 EO chain segments, endowing it with superior hydrophilicity, emulsifying and solubilizing capabilities, wetting and dispersing performance, as well as certain moisturizing properties.

As a formulation additive, the usage of G-18 differs depending on the system. Due to its viscous liquid nature (kinematic viscosity 100~200 mm²/s), it is recommended to heat it to 30~40°C before addition to reduce viscosity, facilitating accurate measurement and dispersion. For aqueous systems, it can be added slowly under stirring; for oil-based systems or formulations containing oils, it is advisable to pre-dissolve it in a small amount of water before mixing with the oil phase for emulsification. The specific dosage should be determined experimentally based on the performance requirements of the target product and formulation compatibility. The following are general reference suggestions for various application areas.

Technical Parameters

Parameter ItemSpecification ValueRemarks
AppearanceColorless to light yellow transparent liquid
Ionic TypeNonionicCompatible with anionic/cationic/nonionic surfactants
HLB Value18Data source: Guoli Chemical Product Database
Active Content≥99%High concentration product
pH Value (1% Aqueous Solution)5.0~7.0Near neutral, mild and non-irritating
Cloud Point (1% Aqueous Solution)>100°CNot prone to precipitation in high-temperature systems
Hydroxyl Value180~200 mgKOH/g
Acid Value≤0.5 mgKOH/g
Moisture Content≤0.5%
Density (25°C)1.05~1.10 g/cm³
Kinematic Viscosity (25°C)100~200 mm²/sViscous liquid, recommend heating before use
Surface Tension (1% Aqueous Solution)35~40 mN/mData source: Guoli Chemical Product Database
Critical Micelle Concentration (CMC)Approx. 0.1~1.0 g/L (25°C)Data source: Guoli Chemical Product Database
Chemical StabilityStable within pH 3~12Unstable under strong acids, bases, and oxidizing agents
Flash Point>150°CNon-flammable

Application Recommendations

Cosmetics and Personal Care Products

Recommended dosage: 1%~5% (of total formulation weight). As an O/W emulsifier and solubilizer, it is suggested to add G-18 to the water phase under stirring before emulsification, heat to 70~75°C, then mix with the oil phase and homogenize. For fragrance solubilization, pre-mix the fragrance with G-18 in a ratio of 1:3 to 1:5, then add to the water phase and stir until clear. Suitable for creams, lotions, facial cleansers, makeup removers, and toners, enhancing product stability and skin feel.

Textile Industry

Recommended dosage: 2%~5% (based on fabric weight) or 0.5~3 g/L (working solution concentration). As an antistatic agent and softening finishing agent, it can be directly prepared into an aqueous solution and applied to fiber surfaces via padding or immersion methods. Treat at 40~50°C for 20~30 minutes, then dry to impart smooth hand feel and antistatic effects to the fabric.

Metalworking Fluids

Recommended dosage: 3%~8% (of concentrate formulation weight). When preparing cutting fluids or grinding fluids, add G-18 to the aqueous concentrate and stir until dissolved, providing both lubrication and rust inhibition. Dilute to a working concentration of 5%~10% before use.

Coatings and Inks

Recommended dosage: 0.2%~1% (of total formulation weight, or 5%~15% based on pigment weight). As a wetting and dispersing agent, it is recommended to add during the grinding stage, dispersing and grinding together with pigments and binders, effectively preventing pigment flocculation and sedimentation, improving storage stability and tinting strength.

Industrial Cleaners

Recommended dosage: 2%~6% (of concentrate formulation weight). It can be used in combination with other nonionic or anionic surfactants, added directly to water and stirred until dissolved. Suitable for hard surface cleaners and industrial degreaser formulations, enhancing wetting, penetration, and detergency.

Polyurethane Foams

Recommended dosage: 0.5%~2% (of total formulation weight). As a foam stabilizer component, premix uniformly into the polyol component during the foaming process to help regulate cell structure, improving foam fineness and physical uniformity.

Precautions

  • Operational Protection: This product is classified under GHS as skin irritant (H315) and serious eye irritant (H319). Protective gloves and goggles must be worn during operation, and work should be carried out in a well-ventilated area to avoid direct contact with skin and eyes.
  • Storage Conditions: Recommended storage temperature 5~30°C, keep container tightly closed, store in a cool, dry, and well-ventilated place, away from strong oxidizing agents and strong acids/bases. This product is hygroscopic; seal promptly after opening.
  • Preheating Treatment: This product is a viscous liquid with poor fluidity at low temperatures. It is recommended to heat to 30~40°C before use for easy pouring and metering, but avoid prolonged heating at high temperatures (above 80°C) to prevent changes in physicochemical properties.
  • Compatibility with Other Ingredients: This product is non-ionic