Question

What are the main components of G-18 glycerol polyoxyethylene ether, polyoxyethyl glycerol ether?

Answer

The main component of G-18 glycerol polyoxyethylene ether is polyoxyethylene (18) glyceryl ether, a polymer obtained by the addition of glycerol with approximately 18 moles of ethylene oxide, with an active content of ≥99%.

Detailed Description

G-18 glycerol polyoxyethylene ether (INCI name: Glycereth-18, CAS number: 31694-55-0) has a core component of a single nonionic surfactant—polyoxyethylene (18) glyceryl ether. It is produced by addition polymerization of natural glycerol (propane-1,2,3-triol) as the initiator with ethylene oxide (EO), with an average degree of ethoxylation n≈18. The general reaction formula can be expressed as: C₃H₅(OC₂H₄)n(OH)₃₋n, where the average value of n is approximately 18.

From the molecular structure, the product possesses both a glycerol backbone (hydrophilic basis) and polyoxyethylene long chains. The glycerol part retains some hydroxyl groups (—OH), while the polyoxyethylene chain introduces a large number of ether bonds (—C—O—C—), together endowing the product with excellent hydrophilicity, solubilizing ability, and interfacial activity. The product appears as a colorless to light yellow transparent viscous liquid, belongs to nonionic surfactants, with an active content of ≥99%, free alcohol content ≤0.5%, high purity and low impurities.

Due to the absence of easily hydrolyzable groups such as ester bonds and amide bonds in the molecular structure, the product maintains chemical stability over a wide pH range of 3~12, and its performance is not significantly affected in acidic, alkaline, or hard water environments. Its HLB value is about 18, cloud point >100°C, and it is highly soluble in water, making it a typical O/W emulsifier and efficient solubilizer.

Technical Parameters

ParameterSpecification/ValueParameterSpecification/Value
CAS Number31694-55-0AppearanceColorless to light yellow transparent liquid
INCI NameGlycereth-18Active Content≥99%
Molecular FormulaC₃H₅(OC₂H₄)n(OH)₃₋n, n≈18Average Molecular Weight800~900
Ionic TypeNonionicHLB ValueAbout 18
pH Value (1% Aqueous Solution)5.0~7.0Cloud Point>100°C
Density (25°C)1.05~1.10 g/cm³Hydroxyl Value180~200 mgKOH/g
Kinematic Viscosity (40°C)100~200 mm²/sAcid Value≤0.5 mgKOH/g
Surface Tension (1% Aqueous Solution)35~40 mN/mWater Content≤0.5%
Free Alcohol Content≤0.5%Refractive Index (25°C)1.455~1.465
Chemical StabilityStable within pH 3~12
Water SolubilityEasily soluble in water

Application Recommendations

This product has a wide range of applications; recommended uses are as follows:

  • Cosmetics and Personal Care: As an O/W emulsifier and solubilizer, suitable for creams, lotions, facial cleansers, makeup removers, and fragrance solubilization systems. Recommended dosage is 1%~5% of the total formula, significantly improving mildness and skin feel.
  • Industrial Cleaners: Utilizing its excellent wetting and detergency, it is suitable for hard surface cleaning and industrial degreasing formulations, and can be compounded with nonionic or anionic surfactants.
  • Coatings and Inks: As an efficient wetting dispersant, typical dosage is 0.5%~3% of the total formula, effectively preventing flocculation and sedimentation of pigments and fillers.
  • Metalworking Fluids: Combining lubrication and anti-rust functions, recommended addition amount is 2%~8% in cutting fluids and grinding fluids.
  • Polyurethane Foam: Used as a foam stabilizer component to help regulate cell structure.

Precautions

  • According to GHS classification, this product is classified as Skin Irritant Category 2 (H315) and Serious Eye Irritant Category 2A (H319). Protective gloves and safety goggles must be worn during operation.
  • Avoid direct mixing with strong oxidizers, concentrated acids, or concentrated alkalis. Degradation may occur under extreme pH (<3 or >12) and high temperature conditions.
  • Recommended storage temperature is 5~30°C. Keep container tightly sealed to prevent moisture absorption. Avoid freezing or high temperature storage.
  • In case of eye contact, immediately flush with plenty of water for at least 15 minutes and seek medical attention; for skin contact, wash with plenty of soap and water.
  • This product is highly hygroscopic; use promptly after opening and ensure sealed storage.