Question

What are the physicochemical technical parameters of Castor Oil Polyoxyethylene Ether EL-12?

Answer
2026-06-06 官方文档 蓖麻油聚氧乙烯醚EL-12

The physicochemical technical parameters of Castor Oil Polyoxyethylene Ether EL-12 (PEG-12 Castor Oil) cover multiple indicators such as appearance, surface activity, solubility, and purity. Its core parameters include an HLB value of 6.8, cloud point of 50~60°C, and effective content ≥99%, making it a low-foaming nonionic surfactant.

Detailed Description

Castor Oil Polyoxyethylene Ether EL-12 (CAS No.: 61791-12-6) has a molecular formula of C57H104O9(C2H4O)n (n≈12), an average molecular weight of about 1460, and appears as a light yellow to yellow transparent oily liquid. It is a nonionic surfactant with excellent chemical stability, maintaining stable surface activity in acidic, alkaline, and hard water media, and has low hygroscopicity. This product is derived from natural castor oil raw materials through an addition polymerization process, exhibiting mild and low-irritation characteristics.

From surface activity parameters, the HLB value of EL-12 is 6.8, indicating relatively strong lipophilicity, making it suitable for use as a water-in-oil (W/O) or auxiliary oil-in-water (O/W) emulsifier. Its 1% aqueous solution has a cloud point of 50~60°C, surface tension of approximately 32~35 mN/m, and critical micelle concentration (CMC) in the range of about 1×10⁻⁴ to 5×10⁻⁴ mol/L, demonstrating excellent interfacial tension reduction capability. The foam characteristic is low foam, meaning it is less prone to foam interference in practical applications.

In terms of solubility and physicochemical tolerance, this product is easily soluble in organic solvents such as ethanol and ether, and is dispersed rather than completely dissolved in water. It has a high effective content (≥99%), acid value ≤1.0, saponification value 105~125 mgKOH/g, hydroxyl value 75~90 mgKOH/g, moisture content ≤0.5%, and free alcohol content ≤2.0%, indicating high purity, low by-products, and stable and reliable quality.

Technical Parameters

Parameter ItemIndex or ValueTest Condition/Remarks
Chemical NamePEG-12 Castor OilCAS No.: 61791-12-6
Molecular FormulaC57H104O9(C2H4O)n, n≈12
Average Molecular Weight~1460
AppearanceLight yellow to yellow transparent oily liquid25°C visual inspection
Ion TypeNonionic
HLB Value6.8
Cloud Point50~60°C1% aqueous solution
Effective Content≥99%Solid content
pH Value5.0~7.01% and 5% aqueous solution
Density1.00~1.05 g/cm³25°C
Acid Value≤1.0 mgKOH/g
Saponification Value105~125 mgKOH/g
Hydroxyl Value75~90 mgKOH/g
Iodine Value45~55 gI₂/100g
Moisture≤0.5%
Free Alcohol≤2.0%
Kinematic ViscosityApprox. 300~500 mm²/s25°C
Low Shear ViscosityApprox. 300~500 mPa·s25°C
Refractive IndexApprox. 1.470~1.47525°C
Surface TensionApprox. 32~35 mN/m1% aqueous solution
Critical Micelle Concentration (CMC)Approx. 1×10⁻⁴ ~ 5×10⁻⁴ mol/L
Flash Point>150°COpen cup method
Solidification Point< -10°C
Foam CharacteristicLow foam
UnsaturationApprox. 1.8~2.2 mol/kgEstimated from iodine value
Chemical StabilityResistant to acid and alkaliStable under general conditions
SolubilityEasily soluble in organic solvents such as ethanol and ether, dispersible in water
Heavy Metal Content≤10 mg/kg
Arsenic Content≤2 mg/kg
Packaging Specification50kg plastic drum, 200kg plastic drum, IBC toteNational standard packaging

Application Suggestions

Since the HLB value of EL-12 is 6.8, with relatively strong lipophilicity, it is recommended for use in formulations requiring a low HLB emulsifier, such as emulsifiable concentrate (EC) pesticide formulations, water-in-oil creams, and metalworking emulsifying oils. In personal care products, it can be compounded with high HLB emulsifiers to achieve broader emulsification adaptability. It is suggested that the HLB value of the compounded system be maintained between 8 and 12 to obtain more stable O/W emulsions. In industrial cleaning formulations, a recommended dosage is 2%~8% (based on active matter), utilizing its dual wetting and emulsifying effects to enhance oil removal performance.

Precautions

  • This product is a non-hazardous substance.