Question

What are the physicochemical technical parameters of Emulsifier A-110, Oleic Acid Polyoxyethylene Ester, OEO-110?

Answer

Emulsifier A-110 (Oleic Acid Polyoxyethylene Ester, OEO-110) is a class of nonionic surfactants with balanced performance. Its physicochemical parameters comprehensively cover appearance, solubility, interfacial properties, and quality indicators, making it precisely adaptable to various industrial formulation needs.

Detailed Description

Emulsifier A-110, chemically named polyethylene glycol monooleate (PEG oleate), is a nonionic surfactant composed of natural oleic acid as the hydrophobic group and polyoxyethylene chains as the hydrophilic group. At room temperature, it appears as a light yellow to yellow transparent oily liquid or paste, with a molecular weight of approximately 708 g/mol. Its HLB value lies between 11 and 12, providing a balanced hydrophilic-lipophilic characteristic that efficiently forms oil-in-water (O/W) emulsions.

This product is readily soluble in water, with a pH value of 5.0~9.0 for a 1% aqueous solution. It exhibits low foaming properties and rapid foam dissipation. The cloud point ranges from approximately 75 to 85°C, indicating stable structure retention even at higher temperatures. In terms of surface chemical performance, the surface tension at 1% concentration and 25°C is about 30 mN/m, and the critical micelle concentration (CMC) is approximately 1.3×10⁻⁴ mol/L, demonstrating excellent interfacial adsorption and micellization capabilities.

From a quality indicator perspective, the product has an active content ≥99%, monoester content ≥95%, diester content ≤5%, free alcohol ≤2%, moisture ≤1.0%, acid value ≤2.0 mgKOH/g, saponification value and hydroxyl value both in the range of 75~85 mgKOH/g, heavy metals (as Pb) ≤10 mg/kg, and arsenic ≤2 mg/kg, ensuring high purity and good safety.

Technical Parameters

Parameter ItemValue / Description
CAS Number9004-96-0
Molecular FormulaC18H34O2·(C2H4O)n
Molecular WeightApprox. 708
AppearanceLight yellow to yellow liquid or paste
Ionic TypeNonionic
HLB Value11~12
Cloud Point75~85°C
Active Content≥99%
pH (1% Aqueous Solution)5.0~9.0
pH (5% Aqueous Solution)5.0~7.5
SolubilityReadily soluble in water
Density (25°C)Approx. 1.00 g/cm³
Kinematic Viscosity (25°C)Approx. 200 mm²/s
Low Shear Viscosity (25°C)Approx. 300 mPa·s
Refractive Index (20°C)1.4600~1.4700
Surface Tension (1%, 25°C)Approx. 30 mN/m
Critical Micelle Concentration (CMC, 25°C)Approx. 1.3×10⁻⁴ mol/L
Melting PointApprox. -5°C
Flash Point (Closed Cup)>200°C
Acid Value≤2.0 mgKOH/g
Saponification Value75~85 mgKOH/g
Hydroxyl Value75~85 mgKOH/g
Iodine Value80~95 gI₂/100g
UnsaturationApprox. 1.4 mol/kg
Moisture≤1.0%
Monoester Content≥95%
Diester Content≤5%
Free Alcohol≤2%
Heavy Metals (as Pb)≤10 mg/kg
Arsenic (As)≤2 mg/kg
Foaming CharacteristicsLow foaming
HygroscopicitySlightly hygroscopic
Chemical StabilityStable at room temperature, avoid strong acids, strong bases, and high temperatures
Alkali ResistanceNot resistant to strong alkalis (Note: structurally stable in acids, bases, and hard water; caution required in strong alkali environments)
Packaging Specifications50kg plastic drum / 200kg plastic drum / IBC tote

Application Recommendations

Based on the above physicochemical properties, Emulsifier A-110 is particularly suitable for the following scenarios:

  • O/W Emulsion Preparation: With an HLB value of 11~12 and low CMC, it quickly spreads and forms stable, fine emulsions in pesticide emulsifiable concentrates, cosmetic creams, and metalworking emulsifying oils.
  • Industrial Cleaning: Its low foaming tendency combined with excellent wetting and penetrating power makes it suitable for spray or circulating system formulations for metal degreasing and hard surface cleaning.
  • Textile Auxiliaries: As a core component in wool lubricants and spin finishes, it utilizes its antistatic and smoothing properties to reduce fiber friction and breakage.
  • Emulsion Polymerization: With high monoester content (≥95%), it ensures uniform particle size and high stability of the product when used as a reactive emulsifier in acrylate, styrene-acrylic, and similar systems.

Precautions

This product is mildly irritating to skin and eyes; it is recommended to wear chemical protective gloves and goggles during operation. Storage temperature should be maintained at 5~35°C, avoiding freezing or deterioration due to high temperatures. Do not store with strong oxidizers or mix with food and feed. Although the product has good structural stability under acidic and alkaline conditions, compatibility and stability assessments are still necessary in strong alkaline environments.