Question

Is polyethylene glycol PEG-800 harmful to humans? Does it have an impact on the environment?

Answer
2026-06-06 官方文档 聚乙二醇PEG-800

Polyethylene glycol PEG-800 is classified as a practically non-toxic substance, posing extremely low safety risks to humans; it exhibits low toxicity to aquatic organisms, is readily biodegradable, and has minimal environmental impact.

Detailed Explanation

Polyethylene glycol PEG-800 (CAS No.: 25322-68-3) is a non-ionic water-soluble polymer that is safe for humans under normal use conditions. According to toxicological study data, its acute oral toxicity LD₅₀ value in rats exceeds 5,000 mg/kg, with no observed mortality at this dose, classifying it as practically non-toxic according to the GHS classification criteria. Skin irritation tests (OECD 404), eye irritation tests (OECD 405), and skin sensitization tests (OECD 406) were all negative, indicating that the product is non-irritating to the skin and eyes and non-sensitizing. Additionally, the Ames bacterial reverse mutation test result was negative, demonstrating its lack of mutagenicity, and no significant target organ toxicity has been reported from long-term exposure.

From an environmental perspective, PEG-800 exhibits low acute toxicity to aquatic organisms (including fish, daphnia, etc.), classifying it as a low-hazard substance. Its octanol/water partition coefficient (LogPow) is low, indicating no potential for bioaccumulation in organisms. More importantly, the product is readily biodegradable and can be rapidly decomposed through biological oxidation upon entering the environment, without long-term persistence in the ecosystem. However, it is worth noting that although the hazard of a single release is limited, large spills into water bodies or soil should still be avoided to prevent short-term load impacts on local ecosystems.

It should be emphasized that PEG-800 is not classified as a hazardous chemical, does not possess flammable or explosive properties (closed cup flash point approx. 240–270 °C), and is safe and convenient to store and use. Long-term application in various fields such as pharmaceutical preparations, personal care products, and industrial processing has fully verified its good physiological safety and environmental compatibility. Under recommended usage conditions, the risks to human health and the environment posed by this product are both controllable and at extremely low levels.

Summary of Toxicological and Ecological Parameters

Test Item Test Method/Subject Result Conclusion
Acute Oral Toxicity Rats, LD₅₀ > 5,000 mg/kg Practically Non-toxic
Skin Corrosion/Irritation Rabbits, OECD 404 Non-irritating Safe
Serious Eye Damage/Irritation Rabbits, OECD 405 Non-irritating Safe
Skin Sensitization Guinea Pigs, OECD 406 Non-sensitizing Safe
Mutagenicity Ames Test (Bacterial Reverse Mutation) Negative Non-mutagenic
Aquatic Toxicity Fish, Daphnia, etc. Low Toxicity Low Hazard
Biodegradability Readily Biodegradable No Persistent Residue
Bioaccumulation Potential LogPow Low (Not Easily Enriched) No Accumulation Risk
Flash Point (Closed Cup) Approx. 240–270 °C Not Flammable

Application Recommendations

Given the excellent safety and environmental characteristics of PEG-800, it is widely used in multiple industries: in the pharmaceutical field as an ointment base, suppository base, and pill excipient; in personal care products as a humectant and emollient; and in industrial processing as a lubricant and mold release agent. Users should follow recommended dosages according to specific application scenarios and refer to the product safety data sheet for handling.

Precautions

  • Operational Protection: Although the product itself is safe, it is recommended to maintain ventilation in the work area, wear chemical safety goggles and protective gloves (e.g., nitrile rubber), and avoid prolonged direct contact.
  • Dust Control: PEG-800 is a white waxy solid; if dust is generated during handling, wear a dust mask (meeting NIOSH N95 standard) to prevent inhalation and discomfort.
  • Heating Operations: If melting the product is required, control heating temperature below the flash point to avoid generating irritating vapors or degradation products, and keep away from ignition sources.
  • Storage Conditions: Store in a cool, dry place at temperatures not exceeding 40 °C, keeping containers tightly sealed to prevent moisture absorption. Keep away from incompatible substances such as strong oxidizers, strong acids, and strong bases.
  • Spill Management: Solid PEG spills may cause slipping hazards; clean up promptly. Large spills should not be discharged directly into drains or the environment; contain with inert materials and dispose of through a qualified treatment facility.
  • First Aid Measures: For skin contact, wash with water and soap; for eye contact, rinse with running water for at least 15 minutes; if ingested, do not induce vomiting, rinse mouth with water, drink 200-300 mL of water, and seek medical attention.