Question

Usage of PEG400MO, Polyethylene Glycol 400 Monooleate?

Answer
2026-05-17 官方文档 PEG400MO,聚乙二醇400单油酸酯

Usage of PEG400MO (Polyethylene Glycol 400 Monooleate) varies by application area. It is typically added directly to the formulation system as an emulsifier, dispersant, or wetting agent, with a recommended dosage generally ranging from 1% to 10% of the total formula weight.

Detailed Description

PEG400MO is a non-ionic surfactant with an HLB value of 11.5 (Source: Guoli Chemical Product Database). It is readily soluble in water, ethanol, and acetone, exhibiting good chemical stability and broad compatibility. Its usage is generally simple; it can be added directly to the aqueous phase or oil phase, or mixed simultaneously with both phases during emulsification. Since the product may thicken or solidify at low temperatures, it is recommended to check the product condition before use. If solidification occurs, gently warm it under 20-40°C and stir thoroughly before use (Source: Guoli Chemical Product Safety Instructions). This does not affect product quality.

In practical formulation operations, there are three main methods for adding PEG400MO: (1) Direct addition to the aqueous phase – add the product proportionally to deionized water, stir until fully dissolved, then mix with the oil phase for emulsification. Suitable for O/W creams, lotions, etc.; (2) Addition to the oil phase – dissolve the product in the oily components, then mix with the aqueous phase. Suitable for formulations requiring pre-dispersion in the oil phase; (3) Phase inversion emulsification – add the product to the oil phase, then slowly add the aqueous phase under high-speed stirring, utilizing the phase inversion process to achieve finer emulsion droplet sizes. Since PEG400MO is a low-foaming surfactant (Source: Guoli Chemical Database), it does not generate excessive foam that interferes with mechanical stirring processes.

This product can be used in combination with non-ionic, anionic, cationic, and amphoteric surfactants (Source: Guoli Chemical Product Instructions). It is recommended to conduct small-scale compatibility tests before formulation. Its critical micelle concentration (CMC) is approximately 0.05 g/L (Source: Guoli Chemical Database), allowing it to exert surface-active effects at low concentrations. Actual usage concentrations should be higher than this value to ensure emulsification or dispersion effects.

Specific Usage and Recommended Dosages by Field

Note: The following recommended dosages are general industry experience values, with no specific dosage data available in the database. Optimal addition levels should be determined through small-scale trials.

Application FieldRecommended Dosage (% of total formula weight)Addition MethodProcess Key Points
Cosmetic creams/lotions2%-6%Can be added to either oil phase or aqueous phaseHeat oil and water phases separately at 60-75°C, mix and homogenize for 3-5 minutes, then stir and cool to below 40°C
Makeup removers/cleansers3%-8%Add to oil phaseCan be mixed at room temperature; ensure thorough stirring
Textile spinning oils5%-15%Add to aqueous phasePrepare with warm water at 40-50°C, dissolve the product first before adding other auxiliaries
Metalworking fluids (cutting/grinding fluids)3%-10%Add to oil phasePremix with base oil, rust inhibitors, etc., then add water to form a concentrate emulsion
Pesticide emulsifiable concentrates/emulsions in water5%-12%Add to oil phasePremix with active ingredients and solvents, then add water for dilution when used
Coatings/inks0.5%-3%Add during grinding stageGrind together with pigments and fillers to promote wetting and dispersion
Industrial cleaners2%-8%Add to aqueous phaseBlend with other surfactants; stir to dissolve at room temperature or with slight heating
Leather fatliquors5%-15%Add to oil phaseBlend with other fatliquoring agents, stir evenly at 40-50°C

Technical Parameters

Parameter NameValueParameter NameValue
AppearanceLight yellow to amber liquidHLB Value11.5
Ionic TypeNon-ionicActive Content≥99%
pH Value (1% aqueous solution)5.0-7.0Cloud Point50-70°C
Acid Value≤5 mgKOH/gHydroxyl Value85-105 mgKOH/g
Saponification Value80-100 mgKOH/gIodine Value70-90 gI₂/100g
Density1.11-1.13 g/cm³Surface TensionApprox. 32 mN/m
Moisture Content≤1.0%Flash Point>200°C
Monoester Content≥90%Diester Content<10%

Source of parameters above: Guoli Chemical Product Database

Application Recommendations

Optimal Application Conditions: PEG400MO is stable in the pH range of 4.5-7.5 (Source: Guoli Chemical Database). The emulsification temperature is recommended to be controlled at 50-75°C. This product may hydrolyze when exposed to strong alkalis (Source: Guoli Chemical Database), so in strongly alkaline formulations, evaluate its stability or appropriately increase the dosage. With an HLB value of 11.5, it is particularly suitable for preparing O/W (oil-in-water) emulsion systems. For preparing W/O emulsions, it is recommended to use it in combination with low-HLB emulsifiers.

Combination Recommendations: This product has excellent compatibility and can be combined with anionic (e.g., sulfonates), cationic, and amphoteric surfactants. In metalworking fluids, it is often used in conjunction with sodium petroleum sulfonate, fatty acid amides, etc. In cosmetics, it can synergize with fatty alcohols, fatty acids, silicone oils, and other ingredients to enhance product stability and skin feel.

Precautions

  • Pre-treatment: The product may thicken or solidify at low temperatures (below 10°C). Before use, gently warm it at 20-40°C and stir thoroughly. Do not heat directly with an open flame.
  • Dissolution operation: This product is readily soluble in water. It is recommended to slowly add it to water under stirring conditions, avoiding large one-time additions that could cause localized high concentration and uneven dissolution.
  • Protective requirements: Although non-irritating to skin (PII=0.0, Source: Guoli Chemical Toxicology Data), it is recommended to wear protective gloves and safety goggles during operation to avoid prolonged direct contact or splashing into eyes.
  • Incompatible combinations: Avoid contact with strong oxidizers (e.g., peroxides, high-concentration nitric acid, perchlorates) (Source: Guoli Chemical Safety Instructions) to prevent vigorous reactions.
  • Storage conditions: Immediately seal the container after use. Store in a cool, dry place at 5-40°C, protecting from moisture absorption. The product is hygroscopic; prolonged exposure to high humidity may cause moisture absorption, affecting its effective content.
  • Dosage determination: Different formulation systems vary greatly in oil phase types, emulsification equipment, and process conditions. It is recommended to conduct a small trial when using for the first time.