Question

What are the physical and chemical technical parameters of PEG600MO (Polyethylene Glycol 600 Monooleate)?

Answer
2026-06-06 官方文档 PEG600MO,聚乙二醇600单油酸酯

PEG600MO (Polyethylene Glycol 600 Monooleate) is a nonionic surfactant with an HLB value of approximately 13.5, combining excellent hydrophilicity and lipophilicity. Its physical and chemical parameters cover multiple dimensions, from appearance and solubility to interfacial chemical properties.

Detailed Description

PEG600MO is a nonionic surfactant produced by the esterification of polyethylene glycol 600 with natural oleic acid. It appears as a light yellow to yellow liquid or paste (freezing point approximately 5~10°C). Its molecular structure features a balanced distribution of hydrophilic groups (polyoxyethylene chain, n≈13) and lipophilic groups (oleate ester group), imparting excellent self-emulsifying ability and broad compatibility. The product is readily soluble in polar solvents such as water, ethanol, and acetone. The cloud point of a 1% aqueous solution is ≥60°C, making it a medium-to-high temperature applicable emulsifier.

The active content of this product is ≥99%, monoester content ≥95%, diester content ≤5%, free alcohol ≤3%, acid value ≤2.0 mgKOH\/g, saponification value 60~80 mgKOH\/g, hydroxyl value 70~95 mgKOH\/g, and iodine value 30~40 gI₂\/100g, indicating controlled unsaturation in the molecule. The pH of a 1% aqueous solution ranges from 5.0 to 7.0, close to the natural pH of human skin, making it suitable for personal care formulations.

In terms of interfacial chemical properties, the surface tension of a 0.1% aqueous solution is approximately 35 mN\/m, and the critical micelle concentration (CMC) is about 0.04 mmol\/L, demonstrating good surface activity efficiency. The product is low-foaming, with a kinematic viscosity of approximately 150 mm²\/s at 40°C and a low-shear viscosity of 150~250 mPa·s at 25°C. The flash point is >200°C, and it is chemically stable under normal conditions, but the product has some hygroscopicity and is not resistant to strong alkalis.

Technical Parameters

Parameter Item Specification\/Index
Product NamePEG600MO \/ Polyethylene Glycol 600 Monooleate
CAS Number9004-96-0
Molecular FormulaC₁₇H₃₃COO(C₂H₄O)ₙH, n≈13
Molecular WeightApproximately 860
Ionic TypeNonionic Surfactant
AppearanceLight yellow to yellow liquid or paste
Freezing PointApproximately 5~10°C
Active Content≥99%
Monoester Content≥95%
Diester Content≤5%
Free Alcohol≤3%
Acid Value≤2.0 mgKOH\/g
Saponification Value60~80 mgKOH\/g
Hydroxyl Value70~95 mgKOH\/g
Iodine Value30~40 gI₂\/100g
Moisture Content≤1.0%
HLB Value13.5
Cloud Point (1% Aqueous Solution)≥60°C
pH (1% Aqueous Solution)5.0~7.0
pH (5% Aqueous Solution)4.5~7.5
Surface Tension (0.1% Aqueous Solution)Approximately 35 mN\/m
Critical Micelle Concentration (CMC)Approximately 0.04 mmol\/L
Density1.11~1.13 g\/cm³
Kinematic Viscosity (40°C)Approximately 150 mm²\/s
Low Shear Viscosity (25°C)150~250 mPa·s
Refractive Index1.466~1.468
Flash Point>200°C
SolubilityReadily soluble in water, ethanol, acetone
Foam CharacteristicsLow foaming
HygroscopicityYes
Alkali ResistanceNot resistant to strong alkalis
Chemical StabilityStable under normal conditions
Heavy Metal Content≤10 mg\/kg
Arsenic Content≤2 mg\/kg
Packaging Specification20 kg woven bag

Application Recommendations

Based on the HLB value of 13.5 and core parameters, PEG600MO is most suitable as an O\/W emulsifier and solubilizer:

  • Cosmetics Field: Recommended for creams, lotions, makeup removers, and facial cleansers. Leveraging its mild pH of 5.0~7.0, it provides stable emulsification and a emollient skin feel.
  • Agrochemical Formulations: Used as an agricultural emulsifier. With a low CMC value (approximately 0.04 mmol\/L), it effectively reduces oil-water interfacial tension, helping to uniformly disperse active ingredients in water-based systems.
  • Metalworking Fluids: Acts as a dual-function emulsifying and lubricating component in cutting fluids and grinding fluids. Its viscosity characteristics (150 mm²\/s at 40°C) can provide auxiliary boundary lubrication.
  • Industrial Cleaning: Utilizes its emulsifying and dispersing ability for mineral oils and animal\/vegetable oils, enhancing the detergency of water-based cleaners. The low-foaming property also facilitates rinsing.
  • Pharmaceutical Industry: Used as a solubilizer for poorly soluble drugs. A hydroxyl value of 70~95 mgKOH\/g and monoester content ≥95% ensure reliable solubilization performance.

Precautions

  • Storage Temperature: Given a freezing point of approximately 5~10°C, storage in winter should be maintained above 5°C to avoid solidification and clumping; recommended storage temperature is 5~30°C.
  • Limited Alkali Resistance: This product is not resistant to strong alkalis and may undergo hydrolysis in strongly alkaline formulations. Evaluate the pH environment of the formulation in advance.
  • Hygroscopicity Handling: The product is hygroscopic. After opening, it should be sealed and stored immediately to prevent quality degradation due to moisture absorption from the air.
  • Safety Protection: May cause skin, eye, and respiratory irritation (GHS classification H315\/H319\/H335). It is recommended to wear safety goggles and nitrile\/chloroprene gloves during operation and use in a well-ventilated area.
  • The above physical and chemical parameters are derived from actual measured data of Guoli Chemical products and are for reference only. Specific batch indicators are subject to the factory inspection report.