Question

How to use polyether L-61?

Answer
2026-05-17 官方文档 聚醚L-61

The method of using polyether L-61 varies depending on the application field, usually by direct addition, premixing and dissolving, or compounding, with a recommended dosage of 0.1% to 5% of the total system weight.

Detailed Description

Polyether L-61 (Poloxamer 181) is a nonionic high-molecular-weight surfactant. It is a viscous liquid at room temperature and maintains stable interfacial activity in acidic, alkaline, and hard water environments. Due to its low HLB value (approximately 1 to 7, tending to be lipophilic), it dissolves relatively slowly in water. It is recommended to premix or predilute it before use to ensure uniform dispersion in the system and to fully exert its emulsifying, defoaming, and dispersing effects.

In practice, polyether L-61 can be used alone or compounded with other surfactants for synergistic effects. For example, in defoamer formulations, it is often combined with high-carbon alcohols, silicone oil, or hydrophobic silica; in metalworking fluids, it is compounded with anionic emulsifiers and rust inhibitors to enhance lubrication and foam resistance. It is recommended to determine the optimal dosage and addition process through small-scale trials to avoid excessive thickening or compatibility issues caused by overuse.

Specific Usage in Various Fields

1. Polyurethane Foam — Stabilizer and Cell Size Regulator

In polyurethane flexible and rigid foam formulations, premix polyether L-61 thoroughly with the polyol component, with a recommended dosage of 0.5% to 2.0% of the polyol weight. Ensure adequate stirring (recommended for at least 10 to 15 minutes) to evenly disperse it in the polyol phase, which helps regulate foam cell structure and prevents collapse and coalescence during foaming. For rigid foam systems, L-61 also improves the compatibility and flowability of components (e.g., blowing agents, flame retardants).

2. Industrial Defoamers — Active Component

Polyether L-61 can be used as the main active ingredient or auxiliary defoaming component in defoamers. To prepare defoamers, mix L-61 with carrier oils (e.g., mineral oil, white oil), hydrophobic particles (e.g., hydrophobic silica), and other synergistic components at 60 to 80°C with stirring until uniform. The amount of L-61 typically accounts for 5% to 30% of the defoamer formulation. The recommended addition level of the finished defoamer in coatings, adhesives, paper white water, and wastewater treatment systems is 0.01% to 0.5% of the total system weight, adjusted based on satisfactory foam elimination and suppression.

3. Water-Based Metalworking Fluids — Lubrication and Anti-Foam Component

In emulsifiable or semi-synthetic metalworking fluid concentrates, add polyether L-61 together with base oils, anionic emulsifiers, and rust inhibitors, with a recommended dosage of 1% to 5% of the total concentrate weight. When using, dilute the concentrate to working concentration (usually 3% to 10%), where L-61 provides boundary lubrication and anti-foaming effects, effectively suppressing foam generated by high-pressure spraying and circulating pumps.

4. Textile Auxiliaries — Low-Foam Wetting Agent and Leveling Agent

In dyeing or pretreatment baths, predisperse polyether L-61 in warm water (40 to 50°C) to form a uniform emulsion before adding to the treatment bath. As a wetting agent, the recommended dosage is 0.1 to 1.0 g/L (based on bath ratio); as a leveling agent, the recommended dosage is 0.5 to 2.0 g/L. Its low-foaming characteristics make it especially suitable for jet dyeing machines and other dynamic circulation equipment, reducing foam interference with dyeing quality and equipment operation.

5. Pesticide Formulations — Emulsifier and Dispersant

In emulsifiable concentrates (EC) or suspension concentrates (SC) of pesticides, mix polyether L-61 with the pesticide technical, solvents, and other emulsifiers. For EC formulations, the recommended dosage is 3% to 10% of the total formulation; for SC formulations, it is recommended to compound with anionic dispersants, with L-61 dosage at 1% to 5% of the total formulation. Ensure thorough mixing to achieve good self-emulsification and dilution stability when the formulation is diluted in the field.

Operational Precautions

  • Premixing and Temperature Control: The viscosity of L-61 increases at low temperatures. In winter or at low temperatures, it is recommended to preheat the product at 25 to 35°C or predilute with warm water before use to facilitate pouring and dispersion.
  • Stirring and Dispersion: Whether adding directly or premixing, ensure thorough stirring for uniform dispersion, using a mechanical stirrer, with stirring time no less than 10 minutes.
  • Dosage Optimization: The optimal dosage varies greatly among different systems. For first-time use, start with a low dosage (e.g., 0.1%) and determine the optimal amount through gradient trials to avoid excessive addition.
  • Compounding Compatibility: L-61 has good compatibility with nonionic, anionic, and cationic surfactants, but it is recommended to conduct small-scale compatibility tests to confirm no precipitation or phase separation.
  • Storage and Handling: Seal the container immediately after use to prevent moisture absorption. If stored for a long time, stir well before use. As a high-molecular-weight polymer, slight stratification may occur after prolonged standing, which is normal.

Safety Operation Reminder

According to the product safety data sheet, polyether L-61 is classified as a skin/eye irritant (GHS Category 2). When handling, wear chemical safety goggles and chemical-resistant gloves (e.g., nitrile rubber), use in a well-ventilated area, and avoid inhaling vapors or mists. In case of eye contact, rinse immediately with plenty of water for at least 15 minutes and seek medical attention. For detailed safety information, refer to the product SDS.