Question

How to use polypropylene glycol PPG-200?

Answer
2026-05-17 官方文档 聚丙二醇PPG-200

How to use polypropylene glycol PPG-200 varies depending on the application; the formulation ratio and process conditions need to be adjusted according to the specific application field.

Detailed Description

Polypropylene glycol PPG-200 (CAS No.: 25322-69-4) is a nonionic polymer with an appearance of a colorless to slightly yellow transparent viscous liquid, a molecular weight of approximately 190~210, and excellent solubility and chemical compatibility. According to the Guoli Chemical product database, PPG-200 is used as a key initiator in polyurethane synthesis and as a functional additive or intermediate in other fields. In practical applications, there is no single fixed usage method; instead, it must be flexibly adjusted based on the target product and process requirements.

In flexible polyurethane foam production, PPG-200 directly participates in the polymerization reaction as a polyol initiator, and needs to be mixed with isocyanates (such as TDI, MDI) according to the formulation ratio, usually with the addition of catalysts, blowing agents, foam stabilizers and other additives. In the lubricant and hydraulic fluid field, PPG-200 is used as a synthetic base oil component, and can be directly added or blended with other base oils; the addition amount is determined based on the viscosity grade and performance requirements of the final product. In release agent applications, PPG-200 is usually diluted with an appropriate solvent to the working concentration and then sprayed or brushed onto the mold surface. In defoamer preparation, PPG-200 is a key raw material, which needs to be compounded with hydrophobic silica, emulsifiers and other agents to form a defoamer masterbatch, and then diluted for use.

In the fine chemical synthesis field, PPG-200, as an important intermediate for nonionic surfactants, needs further modification through chemical reactions such as esterification and etherification, introducing hydrophilic or hydrophobic groups to adjust the HLB value. In cosmetics, PPG-200 acts as a moisturizing and lubricating component, usually added to the formulation in the post-addition stage below 45°C. The recommended dosage is generally between 1% and 10%, and needs to be adjusted according to the skin feel and stability of the specific formulation. According to Guoli Chemical data, PPG-200 has an effective content of ≥99%, a pH value of 5.0~7.0 for a 1% aqueous solution, and a hydroxyl value of 540~590 mgKOH\/g.

Technical Parameters

ParameterSpecification
AppearanceColorless to slightly yellow transparent viscous liquid
Molecular weight190~210
Effective content≥99%
Hydroxyl value540~590 mgKOH\/g
Kinematic viscosity (40°C)30~40 mm²\/s
Density1.004~1.010 g\/cm³
pH value (1% aqueous solution)5.0~7.0
Acid value≤0.10 mgKOH\/g
Moisture content≤0.10%
Flash point (closed cup)≥200°C
Freezing pointApprox. -45°C
HLB valueApprox. 1
Ionic typeNonionic
Foam characteristicsLow foam
SolubilitySoluble in water, readily soluble in organic solvents such as alcohols, esters, and ketones

Application Recommendations

  • Flexible polyurethane foam field: As a polyol initiator directly involved in the formulation reaction, the moisture content must be strictly controlled (product moisture ≤0.10%). When reacting with isocyanates, pay attention to the NCO\/OH ratio calculation. It is recommended to use amine or tin catalysts in combination.
  • Lubricant base oil: Can be used directly or blended with synthetic oils such as esters and PAO. Suitable for formulating high-temperature chain oils, compressor oils, and gear oils. The addition ratio depends on the viscosity grade of the final product.
  • Release agent: It is recommended to dilute with alcohol or ester solvents to a concentration of 10%~30% before spraying. After forming a uniform release film, it can effectively reduce mold fouling.
  • Defoamer: Compound with hydrophobic silica, emulsifiers, etc. to make a defoamer masterbatch. Use at an addition amount of 0.01%~0.5% based on the total system weight.
  • Surfactant synthesis: Utilize its terminal hydroxyl reactivity to introduce functional groups through esterification or etherification reactions to synthesize fatty acid ester polyethers, phosphate esters and other derivatives.
  • Cosmetic formulations: Can be added during the emulsification or cooling stage. Recommended dosage is 1%~10% to provide a refreshing skin feel and good spreadability.

Precautions

  • Storage conditions: Store in a cool (5~35°C), dry, well-ventilated warehouse. Keep the container tightly closed to prevent moisture absorption. Keep away from fire sources and strong oxidizers. The recommended storage period is within 24 months from the date of production.
  • Operational protection: The product has low toxicity but may cause mild eye irritation (GHS classification H319). Wear chemical safety goggles and chemically resistant gloves when handling. Use in a well-ventilated area.
  • Pretreatment recommendations: The viscosity of the product increases at low temperatures. Pre-heat at 20~40°C before use to facilitate pouring and metering, but avoid local overheating.
  • Compatibility testing: It is recommended to conduct small-scale tests before compounding to confirm compatibility with other components and formulation stability.
  • Packaging specifications: Guoli Chemical offers various packaging options including 50 kg plastic drums, 200 kg plastic drums, and IBC totes. Users can choose according to production needs.