Question

How to use Polyethylene Glycol 400 Distearate 400DS? What is the recommended addition amount?

Answer
2026-06-06 官方文档 聚乙二醇双硬脂酸酯400DS

Polyethylene Glycol 400 Distearate 400DS is a white to slightly yellow waxy solid with an HLB value of approximately 7.5. It needs to be melted or dispersed before use, and the recommended addition amount in different applications is 0.5% to 8%.

Detailed Description

Polyethylene Glycol 400 Distearate 400DS (PEG-400 Distearate, CAS No.: 9005-08-7) is a nonionic surfactant. At room temperature, it appears as a white to slightly yellow waxy solid with a melting point range of 40~50°C. Since the product is in solid form, it must be heated to a molten state before use (recommended heating to 50~60°C), then added to the oil phase and mixed thoroughly with other oily components; alternatively, it can be pre-dissolved in organic solvents such as ethanol or isopropyl alcohol before being incorporated into the formulation system.

The product has an HLB value of 7.5, indicating moderate lipophilicity, and it disperses in water rather than completely dissolving. Therefore, when preparing oil-in-water (O/W) emulsions, it is typically used in combination with high-HLB emulsifiers (such as PEG-400 Monostearate) to achieve better emulsifying effects. Its diester content is ≥90%, offering good chemical stability and stable performance across a wide pH range, but direct contact with strong alkaline environments should be avoided.

As a low-foaming product, PEG-400DS exhibits multiple functions in formulations, including emulsification, thickening, and dispersion. It can be well compounded with anionic, cationic, and amphoteric surfactants, providing high formulation flexibility.

Application Recommendations

The following are recommended addition amounts for various industrial applications (based on industry general reference ranges, sourced from Guoli Chemical formulation application experience):

Application FieldSpecific ProductRecommended Addition Amount (wt%)Function
Personal Care & CosmeticsCreams, Lotions1.0%~4.0%Primary/Co-emulsifier, Thickener
Personal Care & CosmeticsShampoos, Conditioners0.5%~2.0%Thickening, Conditioning, Pearlizing Stability
Personal Care & CosmeticsSunscreens1.5%~3.0%Emulsification Dispersion, Water Resistance Improvement
Household DetergentsFabric Softeners2.0%~5.0%Softening Conditioning, Thickening
Household DetergentsLiquid Detergents0.5%~2.0%Thickening, Foam Stabilization
Textile AuxiliariesSoftening Finishing Agents3.0%~8.0%Softener Component, Antistatic
Metalworking FluidsCutting Fluids, Emulsified Oils2.0%~6.0%Emulsifier, Lubrication Additive
Plastics & Rubber ProcessingInternal Lubricants, Mold Release Agents0.2%~1.5%Flow Improvement, Anti-sticking

The above recommended addition amounts are reference ranges. The specific dosage should be determined through small-scale optimization based on the performance requirements of the target formulation, characteristics of the compounding system, and process conditions.

Precautions

  • Preheat Melting: The product is a waxy solid. It is recommended to heat it to melting at 50~60°C before use, avoiding local overheating that may cause decomposition.
  • Addition Sequence: In emulsification formulations, it is suggested to first add this product to the oil phase and melt it uniformly, then proceed with oil-water emulsification.
  • Compounding Use: With an HLB value of 7.5, the emulsifying capacity is limited when used alone for O/W emulsification. It is recommended to compound with high-HLB emulsifiers to achieve a more stable emulsion system.
  • pH Application Range: It is stable within a pH range of 3~10 but not resistant to strong alkaline environments. Direct coexistence with high-concentration strong bases in the formulation should be avoided.
  • Storage Conditions: Store in a cool, dry place with ambient temperature controlled at 5~40°C. Keep sealed and moisture-proof, away from open flames and strong oxidizers.
  • Operational Protection: Under normal use conditions, it has high safety. It is recommended to wear protective gloves during operation to avoid inhalation of dust.