Question

What is OP-21 Octylphenol Ethoxylate

Answer
2026-05-17 官方文档 OP-21辛基酚聚氧乙烯醚

OP-21 Octylphenol Ethoxylate is a high-performance nonionic surfactant synthesized by the addition polymerization of octylphenol and ethylene oxide. It appears as a white to light yellow waxy paste, with excellent emulsifying, wetting, dispersing, and detergency capabilities.

Detailed Description

OP-21, full name Octylphenol Ethoxylate (21) (CAS No.: 9036-19-5), is a classic nonionic surfactant produced by Guoli Chemical. Its molecular structure combines a hydrophobic octylphenol group with a hydrophilic polyoxyethylene chain (approximately 21 EO units), endowing the product with excellent surface activity and broad application adaptability.

As a nonionic surfactant, OP-21 does not ionize in solution and exhibits excellent compatibility with anionic, cationic, and amphoteric surfactants. Additionally, it maintains stable surface activity and functionality in acid, alkali, and hard water systems, demonstrating strong chemical tolerance. This enables reliable performance under complex industrial conditions.

OP-21 has high active ingredient content and excellent usage efficiency, helping users reduce formulation addition amounts and lower overall costs. It should be noted that this product is classified as a skin irritant (Category 2) and an eye irritant (Category 2A), and may pose potential hazards to the reproductive system (Category 2). It is also toxic to aquatic life with long-lasting effects. Safety operating procedures must be strictly followed during use.

Technical Parameters

ParameterValue
Product NameOP-21 Octylphenol Ethoxylate
AliasEmulsifier OP-21, Octylphenol Ethoxylate (21), Polyoxyethylene (21) Octylphenyl Ether
CAS No.9036-19-5
Ionic TypeNonionic Surfactant
AppearanceWhite to light yellow waxy paste (consistency varies with temperature)
pH (1% aqueous solution, 25°C)6.0–8.0
Flash Point (Closed Cup)>150°C
Oral LD50 (Rat)>2000 mg/kg
Dermal LD50 (Rabbit)>2000 mg/kg
Fish 96h LC501–10 mg/L
Daphnia 48h EC501–10 mg/L
Algae 72h ErC501–10 mg/L
GHS ClassificationSkin Irritation Category 2 / Eye Irritation Category 2A / Reproductive Toxicity Category 2 / Acute and Chronic Aquatic Toxicity Category 2

Application Suggestions

OP-21, with its excellent emulsifying ability and wetting penetration, is widely used in multiple industrial fields:

  • Textile Dyeing and Printing: Used as a penetrating agent, scouring agent, and leveling agent to improve fabric pretreatment effects and dyeing uniformity.
  • Leather Processing: Used in degreasing and fatliquoring processes to help remove natural oils from leather, improving softness and hand feel.
  • Papermaking and Waste Paper Deinking: Used as a wetting dispersant to accelerate ink detachment and dispersion, enhancing deinking efficiency.
  • Detergent Industry: As an active component in household and industrial detergents, providing excellent detergency, emulsification, and wetting abilities.
  • Pesticide Formulations: Serves as an emulsifier in emulsifiable concentrates and oil-in-water emulsions, ensuring stable dispersion of active ingredients.
  • Coatings and Inks: Acts as a pigment wetting dispersant, reducing milling time and preventing pigment flocculation.
  • Emulsion Polymerization: Used as an emulsifying stabilizer to ensure smooth polymerization and uniform dispersion of latex particles.
  • Metalworking Fluids: Enhances cooling, lubrication, and cleaning performance, effectively removing mineral oils and animal/vegetable fats.

Precautions

Safety Protection: Operators must wear protective gloves, protective clothing, goggles, and face shields. In case of skin contact, wash with plenty of water and soap; if it enters the eyes, rinse carefully with water for several minutes, remove contact lenses if present, and continue rinsing. If irritation persists, seek medical attention.

Environmental Disposal: This product is toxic to aquatic life, and the octylphenol group is persistent in the environment and has endocrine-disrupting properties. Do not discharge waste into water bodies; dispose of as hazardous waste according to local/national/international regulations. Spills should be collected promptly.

Storage Requirements: Store in a locked place and keep away from unauthorized personnel. Obtain and read the Safety Data Sheet (SDS) before use to fully understand the product's hazardous characteristics.