Question

Precautions for using Polyethylene Glycol PEG-4000/6000?

Answer
2026-05-27 官方文档 聚乙二醇PEG-4000/6000

When using Polyethylene Glycol PEG-4000/6000, special attention should be paid to moisture-proof sealing, dust explosion prevention, personal protection, and mild operating conditions. Although this product is a low-toxicity non-hazardous substance, its fine dust has potential explosion risks, and strict standard operation is required.

Detailed Explanation

Polyethylene Glycol PEG-4000/6000 is a non-ionic high-molecular polymer produced by Guoli Chemical, appearing as a white to slightly yellow waxy solid or flakes. This product remains stable over a wide pH range, exhibiting excellent resistance to acids, alkalis, and hard water environments. It has stable chemical properties and high safety (acute oral toxicity LD50 > 5000 mg/kg, classified as practically non-toxic). However, during use, three aspects require particular attention: moisture absorption control, dust explosion safety, and personal protection.

First, this product has strong hygroscopicity. If not sealed promptly after opening, it will quickly absorb moisture from the air, leading to caking or property changes, affecting subsequent use. Second, PEG-4000/6000 can easily generate fine dust during operations such as cutting, grinding, and sieving. Its dust explosion class is St1, and the minimum ignition temperature (MIT) of the dust cloud is > 400°C. If the dust reaches a certain concentration in the air and encounters an ignition source, there is a risk of explosion. Therefore, open flames, sparks, and high-temperature surfaces must be strictly prohibited in the operating area. All equipment must be reliably grounded and anti-static measures should be taken.

In terms of applications, PEG-4000/6000 has mature applications in multiple fields such as pharmaceutical ointment bases, suppository carriers, toothpaste humectants, and textile lubricants. Depending on the specific use, its pretreatment methods also need to be differentiated: in the pharmaceutical and daily chemical sectors, it usually requires pre-melting (melting point approx. 54-63°C) or dissolution before adding to the formulation; in the textile and paper industries, it is often used in the form of an aqueous solution. When preparing, it is recommended to slowly add to warm water under stirring to avoid clumping from a single large addition.

Key Safety Parameters

Parameter ItemValue\/Description
Hazard ClassificationNot classified as hazardous substance or mixture (GHS and EC No 1272\/2008)
Dust Explosion ClassSt1 (Weak explosiveness)
Minimum Ignition Temperature (MIT) of Dust Cloud> 400°C
Flash Point (Open Cup)> 240°C
Acute Oral Toxicity LD50 (Rats)> 5000 mg\/kg (Practically non-toxic)
Recommended Storage Temperature10-30°C, in a cool, dry, and ventilated place
AppearanceWhite to slightly yellow waxy solid or flakes

Application Suggestions

Pharmaceutical Industry Use: When used as an ointment base or suppository carrier, it should be heated and melted in a clean environment (recommended water bath heating to 60-70°C) to avoid local overheating leading to molecular chain degradation. When used as a pill carrier for dripping pills, the melting temperature and the cooling liquid temperature must be precisely controlled to achieve the desired pill shape and drug release profile.

Daily Chemical Industry Use: In toothpaste formulations, the recommended addition amount is 3%-8%, partially replacing glycerin to play a moisturizing and anti-cracking role. In shampoos and body washes, the recommended dosage is 1%-5%, which can be directly added to the surfactant system under gentle stirring, effectively reducing system irritation and enhancing smoothness.

Textile and Industrial Lubrication: When used as an antistatic agent and lubricant for textiles, it is usually formulated into a 5%-20% aqueous solution. It is recommended to use deionized water and dissolve under stirring at a temperature of 40-50°C. The recommended addition amount in metalworking quenchants needs to be determined by debugging according to the cooling curve requirements, generally starting from 3%-10% for optimization.

Pesticide Formulations: As a dispersing carrier for wettable powders and water-dispersible granules, the recommended dosage is 5%-15% of the total weight of the formulation. Its good water solubility and dispersibility help the active ingredients rapidly disintegrate and uniformly suspend upon dilution.

Precautions

  • Moisture-proof Sealing: After opening the bag and taking out the material, immediately tie the bag tightly or transfer it to a sealed container to prevent the product from absorbing moisture and caking. Prolonged exposure to high humidity environments may cause the product to absorb water, affecting weighing accuracy and use effects.
  • Explosion-proof Operation: During large-scale feeding, sieving, or conveying processes, explosion-proof electrical equipment should be used. The workplace should be equipped with a dust collection system. Open flames are strictly prohibited, and all equipment must be reliably grounded to prevent static electricity accumulation.
  • Personal Protection: During operation, it is recommended to wear dust masks (FFP2 standard or equivalent protection level), nitrile rubber protective gloves, and chemical safety goggles. After operation, thoroughly wash hands and exposed skin. Eating, drinking, and smoking are prohibited in the workplace.
  • Incompatible Materials: Keep away from strong oxidizing agents (such as peroxides, potassium permanganate, concentrated nitric acid, etc.). Contact with strong oxidizing agents may cause violent reactions.
  • Melting Operation: When heating and melting is required for use, avoid temperatures exceeding 150°C. Prolonged high temperature may cause thermal degradation of the polymer, generating irritating gases and affecting product performance.
  • Waste Disposal: This product does not contain environmentally persistent toxic substances. Waste disposal should follow local environmental regulations. It can be incinerated for heat recovery or treated biologically before discharge. Direct discharge into water bodies or soil is strictly prohibited.