Question

What are the physicochemical technical parameters of PEG600DO (polyethylene glycol 600 dioleate)?

Answer
2026-06-06 官方文档 PEG600DO,聚乙二醇600双油酸酯

The physicochemical technical parameters of PEG600DO (polyethylene glycol 600 dioleate) cover core indicators such as appearance, HLB value, cloud point, density, viscosity, and surface tension. The following is a complete parameter table based on the product database of Guoli Chemical.

Detailed Description

PEG600DO (CAS No.: 9004-96-0) is a nonionic surfactant with a molecular formula of C36H66O4(C2H4O)n (n≈13) and a molecular weight of approximately 1100. Its molecular structure consists of a hydrophilic polyethylene glycol (PEG-600) chain segment and two lipophilic oleic acid groups. This diester structure endows the product with excellent emulsifying, dispersing, and wetting capabilities. The product appears as a light yellow to yellow liquid, with a freezing point below 0°C, remaining liquid at room temperature for easy handling and formulation.

In terms of emulsification performance, the diester content is ≥95%, monoester content ≤5%, free alcohol content ≤3%, and active ingredient content ≥99%, indicating high purity. The HLB value (hydrophilic-lipophilic balance) is 10~11, falling within the O/W (oil-in-water) emulsifier category. It is dispersible in water and soluble in organic solvents such as ethanol and acetone, showing good compatibility with anionic, cationic, and nonionic systems. The cloud point range is 55~65°C, and its low-foaming property offers significant advantages in industrial cleaning applications.

From a safety and stability perspective, the product has a flash point >200°C (closed cup), making it non-flammable; the acute oral toxicity LD50 is >5000 mg/kg, classifying it as practically non-toxic; it is chemically stable and maintains activity in acid, alkali, and hard water media, but its alkali resistance is rated as "poor", requiring careful evaluation in strongly alkaline formulations. This product is classified as a non-hazardous substance, with relatively lenient storage and transportation conditions, recommended storage temperature being 5~40°C.

Technical Parameters

Parameter Item Value Remarks
Appearance Light yellow to yellow liquid Visual inspection
CAS No. 9004-96-0
Molecular Formula C36H66O4(C2H4O)n, n≈13
Molecular Weight Approx. 1100
Ionic Type Nonionic
HLB Value 10~11 O/W emulsifier
Cloud Point 55~65 °C 1% aqueous solution
Active Content ≥99%
pH (1% aqueous solution) 5.0~7.0 25°C
pH (5% aqueous solution) 4.5~7.5 25°C
Density 1.11~1.13 g/cm³ 20°C
Kinematic Viscosity 150~250 mm²/s 40°C
Refractive Index 1.466~1.468 20°C
Flash Point >200 °C Closed cup method
Freezing Point <0 °C
Surface Tension 30~35 mN/m 25°C, near critical micelle concentration
Critical Micelle Concentration (CMC) 0.01~0.1% (w/v) 25°C
Acid Value ≤2 mg KOH/g
Saponification Value 90~110 mg KOH/g
Hydroxyl Value ≤10 mg KOH/g
Iodine Value 40~60 g I₂/100g
Moisture Content ≤1.0%
Diester Content ≥95%
Monoester Content ≤5%
Free Alcohol ≤3%
Solubility Dispersible in water, soluble in ethanol and acetone
Foaming Characteristics Low foaming
Chemical Stability Stable In acid, alkali, and hard water media
Alkali Resistance Poor Evaluate in strongly alkaline environments
Hygroscopicity Slightly hygroscopic