Question

How to use isotridecyl phosphate ester E-1306P? What is the recommended dosage?

Answer
2026-06-06 官方文档 异构十三醇磷酸酯E-1306P

Isotridecyl phosphate ester E-1306P is an acidic anionic phosphate ester surfactant, easily soluble in water. It is usually added directly or pre-diluted into the formulation system. The recommended dosage varies greatly depending on the application area, generally ranging from 1% to 15% of the total system amount. The optimal dosage should be determined through orthogonal experiments.

Detailed Description

Isotridecyl phosphate ester E-1306P (CAS: 9043-30-5) is an anionic surfactant produced by phosphation of isotridecyl polyoxyethylene ether (n≈6). It appears as a pale yellow transparent viscous liquid with an active content ≥95% and is easily soluble in water. It combines the extreme pressure lubricity of phosphate ester groups with the penetrating and wetting properties of EO chains, making it a multifunctional additive.

According to the Guoli Chemical product database, the HLB value of this product is between 7.0 and 9.0, classifying it as a lipophilic-hydrophilic balanced surfactant. It can serve both as a co-emulsifier in O/W emulsification systems and as a lubrication and corrosion inhibition component in concentrates. The pH of a 1% aqueous solution is 5.0~7.0 (near neutral), but at 5% concentration, the pH drops to 2.0~4.0 (acidic). Therefore, attention must be paid to the acid-base compatibility of the system when preparing high-concentration premixes.

In terms of usage, E-1306P can be directly added to the formulation via cold blending or warm mixing (recommended operating temperature not exceeding 40°C), or it can be pre-diluted with deionized water to 10%~20% concentration before addition to facilitate uniform dispersion. It is recommended to add slowly under stirring to avoid local high concentration leading to gelation or precipitation.

Technical Parameters

ParameterValue
Ionic typeAnionic
Appearance (25°C)Pale yellow transparent viscous liquid
Active content≥95%
HLB value7.0~9.0
pH of 1% aqu. solution5.0~7.0
pH of 5% aqu. solution2.0~4.0
Density (25°C)1.05~1.10 g/cm³
Kinematic viscosity (25°C)200~500 mPa·s
Surface tension (1‰ aqu. solution)35~40 mN/m
Free phosphoric acid≤0.5%
Monoester content50%~70%
Diester content25%~40%
Water solubilityEasily soluble in water
Foam characteristicsLow foam
Alkali resistanceGood
Flash point>100°C

Application Recommendations

The following are empirical reference dosage ranges for various application fields (Source: Guoli Chemical database product data does not provide specific dosage; the following are industry general recommendations. Actual dosage must be verified through formulation experiments):

Application FieldFunctional RoleRecommended Dosage (% of total formulation)
Metalworking fluids (emulsifiable oils/semi-synthetics/full synthetics)Extreme pressure lubricant, corrosion inhibitor2%~8%
Industrial alkaline cleanersAlkali-resistant penetrant, degreaser3%~10%
Textile pretreatment (scouring agents/penetrants)Penetration promotion, impurity removal1%~5%
Leather degreasing and fatliquoringEmulsifying degreasing, softening aid2%~6%
Pesticide emulsifiable concentrates/emulsions in waterEmulsifying dispersant5%~15% (proportion in total emulsifier amount)
Electroplating bath enhancementWetting dispersion, auxiliary brightening0.1%~1%

Blending key points:

  • Metalworking fluids: Recommended to be used in combination with sulfonates, amides, and other anionic/nonionic additives to achieve synergistic effects. Add directly to the concentrate and stir until uniform. Dilute at a ratio of concentrate to water 1:10 to 1:30 for use.
  • Alkaline cleaners: This product has good alkali resistance and is compatible with alkaline components such as sodium hydroxide and sodium metasilicate. It is recommended to add it last and stir until the system is clear and transparent. In high-alkalinity systems, it can be used together with nonionic penetrants (e.g., isotridecyl alcohol ether series).
  • Textile pretreatment: Usually compounded with alkali-resistant penetrant JFC, etc., used in scouring baths. It is recommended to first dissolve with warm water (30°C~40°C) under stirring before adding to the main bath to avoid direct contact with high-concentration alkali liquor.
  • Pesticide formulations: As an anionic emulsifier component, it is often combined with nonionic emulsifiers (e.g., castor oil polyoxyethylene ether, alkylphenol polyoxyethylene ether) in a ratio of 1:1~1:3 to optimize emulsion stability.

Precautions

  • Acidic nature: The concentrate and high-concentration aqueous solutions of this product are acidic (5% concentration pH 2.0~4.0). Avoid direct contact with reactive metals (e.g., aluminum, zinc) during blending. Use stainless steel, polyethylene, or enamel containers.
  • Compatibility test: Precipitation or turbidity may occur when compounded with cationic additives. Conduct a small-scale compatibility test before use.
  • Protective requirements: Always wear impermeable gloves and chemical safety goggles during operation to avoid skin and eye contact. Refer to product SDS for detailed safety information.
  • Storage conditions: Recommended storage temperature 5°C~40°C, avoid freezing. Keep container tightly closed, away from strong oxidizers and strong bases. Best used within the shelf life.
  • Addition sequence: Generally recommended to add E-1306P after pre-mixing the aqueous phase to avoid local overheating caused by direct mixing with high-concentration acid or alkali.