Question

What are the physicochemical technical parameters of Polyether F-38?

Answer
2026-06-06 官方文档 聚醚F-38

Polyether F-38 is a non-ionic surfactant with an HLB value as high as 30.5. At room temperature, it is a colorless to light yellow transparent liquid, featuring low foaming, easy solubility in water, and excellent chemical stability. Its molecular weight of approximately 5000 makes it perform outstandingly in emulsification and dispersion applications.

Detailed Description

Polyether F-38 (CAS No.: 9003-11-6), chemically named polyoxyethylene-polyoxypropylene block copolymer, also known as Poloxamer 108. Its molecular structure is HO(C₂H₄O)x(C₃H₆O)y(C₂H₄O)xH, belonging to the non-ionic surfactant category. It appears as a colorless to light yellow transparent liquid, slightly hygroscopic, with a freezing point of about -10°C. At low temperatures, it may solidify or become turbid, but it can be restored by warming and stirring without affecting performance.

This product exhibits excellent surface activity, with a cloud point of greater than 100°C for a 1% aqueous solution, a surface tension of approximately 43 mN/m at 0.1% concentration (25°C), and a critical micelle concentration of about 0.1% w/v, indicating it can effectively reduce interfacial tension at low concentrations. Meanwhile, the product generates low foam volume, making it a low-foaming type suitable for scenarios requiring rapid defoaming or low-foam processes. It has good chemical stability in acid, alkali, and high-hardness water environments, but is incompatible with strong oxidizing agents.

Technical Parameters

Parameter ItemSpecification/ValueRemarks
CAS No.9003-11-6
Molecular WeightApprox. 5000
AppearanceColorless to light yellow transparent liquid
Ionic TypeNon-ionic
HLB Value30.5Extremely hydrophilic
Cloud Point (1% Aqueous Solution)>100°C
pH Value (1% Aqueous Solution)5.0~8.0
pH Value (5% Aqueous Solution)5.0~7.5
Active Content≥99%
Moisture Content≤0.05%
Density (25°C)1.00~1.10 g/cm³
Kinematic Viscosity (25°C)Approx. 950 mm²/sLow shear viscosity approx. 950 mPa·s
Refractive Index (25°C)1.452~1.457
Freezing PointApprox. -10°CMay become turbid or solidify at low temperatures
Flash Point>200°CNon-flammable
Hydroxyl Value22.0~28.0 mg KOH/g
Acid Value≤0.05 mg KOH/g
Saponification Value≤0.5 mg KOH/g
Iodine Value≤0.5 g I₂/100g
Unsaturation≤0.05 mol/kg
Surface Tension (0.1%, 25°C)≈43 mN/m
Critical Micelle Concentration (CMC)Approx. 0.1% w/v
SolubilityEasily soluble in water
Foaming CharacteristicsLow foaming
Heavy Metals (as Pb)≤10 mg/kg
Arsenic (As)≤2 mg/kg
Chemical StabilityStableAvoid contact with strong oxidizing agents
Packaging Specification20kg woven bag
Shelf LifeOne year (unopened, 5~40°C)

Application Suggestions

With an ultra-high HLB value of 30.5 and excellent surface activity, Polyether F-38 is particularly suitable as an oil-in-water (O/W) emulsifier and efficient wetting dispersant. In the polyurethane industry, it serves as a core reactive component for flexible foam, rigid foam, and elastomers; in the synthesis of defoamers and crude oil demulsifiers, it acts as a key intermediate; in coatings and adhesives, it functions as a modifying component to enhance flexibility and adhesion; in textile auxiliaries, paper chemicals, and metalworking fluids, it plays roles in leveling, antistatic, dispersing, and lubricating. The recommended dosage should be determined through specific formulation experiments.

Precautions

  • Storage Temperature: Store in a cool, dry, and well-ventilated place at 5°C~40°C. If solidified at low temperatures, it can be restored by warming and stirring without affecting quality.
  • Incompatibilities: Avoid contact with strong oxidizing agents; it does not decompose under normal conditions, but may produce CO, CO₂, and irritating fumes when burned.
  • Safe Handling: Although it is low-toxicity, non-skin-irritating, and non-sensitizing, it is recommended to wear protective goggles and gloves during operation to avoid prolonged exposure. If it comes into contact with eyes, it may cause reversible conjunctival redness and swelling; flush immediately with plenty of water for at least 15 minutes and seek medical attention.
  • Environmental Disposal: Readily biodegradable (OECD 301B >60%), discharge after wastewater treatment to meet standards, and dispose of waste packaging through qualified treatment units.