Question

How to use Stearic Acid Polyoxyethylene Ether SG-40? What is the recommended dosage?

Answer
2026-06-06 官方文档 硬脂酸聚氧乙烯醚SG-40

Stearic Acid Polyoxyethylene Ether SG-40 is a high HLB value (16-17) O/W nonionic emulsifier, appearing as a white waxy solid at room temperature. It needs to be melted by heating before use. The recommended dosage varies significantly across different fields, generally ranging from 0.1% to 10%.

Detailed Description

Stearic Acid Polyoxyethylene Ether SG-40 (CAS: 9004-99-3) has a melting point of approximately 48-52°C and appears as a solid wax at room temperature. Before use, it must be heated to above 50°C to melt into a liquid, and then mixed with other components in the formulation. With its high HLB value of 16-17 and strong hydrophilicity (cloud point >100°C), it is particularly suitable for preparing oil-in-water (O/W) emulsion systems. The product has an active content of ≥99%, and the pH of a 1% aqueous solution is 5.0-7.0. It is chemically stable, resistant to acids, alkalis, and hard water.

In practical operation, it is recommended to heat SG-40 together with the oil phase components to 55-65°C. After complete melting and thorough stirring, emulsify with the water phase. For systems requiring fine emulsification (such as cosmetic creams), a homogenization emulsification process is recommended, with emulsification temperature controlled at 60-70°C. After emulsification, cool down slowly to obtain a fine and stable emulsion. SG-40 is a low-foam surfactant with good compatibility. It can be used in combination with anionic, cationic, and amphoteric surfactants to achieve synergistic effects.

SG-40 has good safety, with an acute oral toxicity LD50>5000 mg/kg. It is non-irritating to skin and eyes, and non-sensitizing. No special protection is required during use, but it is still recommended to wear gloves and goggles for basic labor protection. The product has a shelf life of 12 months and should be stored in a cool, dry environment at 5°C~35°C, avoiding storage with strong oxidants.

Recommended Dosage in Various Fields (General Industry Reference Values)

The following dosages are general industry reference ranges (data source: Guoli Chemical Product Database application classification combined with industry practice). The specific dosage should be determined through experiments based on the formulation system and process requirements:

Application Field Functional Role Recommended Dosage (by total formulation weight) Usage Method
Cosmetic Creams/Lotions O/W Emulsifier, Solubilizer 1.0% ~ 5.0% Heat with oil phase to melt, homogenize to emulsify
Shampoo/Body Wash Thickening Aid, Emollient 0.5% ~ 2.0% Hot addition method, add to surfactant phase
Textile Softener/Antistatic Agent Softening, Antistatic, Leveling 1.0% ~ 3.0% Dissolve in water to prepare working solution, pad or immerse
Metalworking Fluids (Cutting Fluids/Grinding Fluids) Emulsifier, Lubricating Component 3.0% ~ 8.0% Compound with base oil, rust inhibitor, etc., then add water to emulsify
Pesticide Emulsifier Emulsifier, Dispersion Carrier 3.0% ~ 10.0% Mix with pesticide active ingredient and solvent to prepare emulsifiable concentrate or microemulsion
Paper Deinking Agent/Softener Deinking Promotion, Paper Softening 0.1% ~ 1.0% Dilute and add to pulp system

Application Suggestions

Cosmetic Systems: With an HLB value of 16-17, SG-40 is suitable for compounding with low HLB emulsifiers (such as Glyceryl Monostearate, HLB approx. 3.8) to obtain a composite emulsifier with an HLB value of 8-12, which is suitable for most creams and lotions. Its monoester content is ≥90%, providing high emulsification efficiency. The prepared cream is fine and glossy with a refreshing and non-greasy skin feel.

Industrial Systems: In metalworking fluids, SG-40 maintains long-term emulsion stability in high-salt and high-alkali formulations due to its excellent electrolyte resistance and chemical stability, making it especially suitable for full-synthetic and semi-synthetic cutting fluid formulations. In the textile industry, SG-40 imparts good antistatic properties and a soft hand feel to synthetic fibers, reducing hairiness and breakage during spinning.

Compounding Synergy: The nonionic nature of SG-40 allows it to be freely compounded with various ionic surfactants. For example, compounding with anionic emulsifiers can improve the salt tolerance stability of the emulsion; compounding with cationic softeners can improve the overall hand feel of fabric finishes.

Precautions

  • Heating Temperature Control: During melting, it is recommended to use a water bath or jacket heating to 55-65°C to avoid local overheating, which may cause product decomposition or color deepening.
  • HLB Value Matching: When used as a single emulsifier, the high HLB value of SG-40 is only suitable for O/W emulsion systems. For preparing W/O emulsions, it must be compounded with low HLB value emulsifiers.
  • Low Foam Characteristics: SG-40 itself has very low foam. If the formulation requires rich foam (such as shampoo), it needs to be combined with high-foam surfactants (such as AES, betaines).
  • Moisture Absorption Protection: The melting point is about 48-52°C. During high-temperature summer storage, caking may occur, which is a normal physical change and does not affect product quality. Just heat and melt normally before use. After opening, seal tightly to prevent moisture absorption.
  • Dosage Subject to Experiment: The above recommended dosages are industry reference ranges. The actual optimal dosage should be determined through orthogonal experiments or gradient experiments based on the specific formulation system.