Question

What are the physicochemical technical parameters of tristyrylphenol polyoxyethylene ether 600-2 and 600-1?

Answer

Tristyrylphenol polyoxyethylene ether 600-2/600-1 is a nonionic surfactant with an HLB value of approximately 11.5 and a cloud point of 50~60°C. It exhibits excellent emulsifying, dispersing, and wetting properties and is widely used in pesticides, textiles, and industrial cleaning.

Detailed description

Tristyrylphenol polyoxyethylene ether 600-2 and 600-1 series (CAS No.: 99734-09-5) are nonionic surfactants prepared by using tristyrylphenol as the hydrophobic group and through addition polymerization of ethylene oxide. The molecular formula is C₆H₅C(C₈H₈)₃O(C₂H₄O)nH, with an average EO number of approximately 9~10 and a molecular weight of about 824. The product is a light yellow to brownish-yellow viscous liquid at room temperature, with a melting point below -10°C. It is readily soluble in water and polar organic solvents such as alcohols and ketones, and also exhibits good dispersibility in non-polar media like mineral oil.

The active content of the product is ≥99%, with free alcohol ≤3% and moisture ≤1.0%. It is chemically stable and maintains activity in acid, alkali, and electrolyte systems. It is a low-foaming surfactant. The flash point is above 150°C, and it is not classified as a flammable liquid. Storage conditions are recommended to be controlled at 5~35°C, avoiding repeated freeze-thaw cycles.

Technical parameters

Parameter itemTechnical indicatorData source
Appearance (25°C)Light yellow to brownish-yellow liquidGuoli Chemical Product Database
Ionic typeNonionicGuoli Chemical Product Database
CAS No.99734-09-5Guoli Chemical Product Database
Molecular formulaC₆H₅C(C₈H₈)₃O(C₂H₄O)nH, n≈9-10Guoli Chemical Product Database
Molecular weightApproximately 824Guoli Chemical Product Database
Active content≥99%Guoli Chemical Product Database
pH value (1% aqueous solution, 25°C)5.0~7.0Guoli Chemical Product Database
pH value (5% aqueous solution, 25°C)5.0~7.0Guoli Chemical Product Database
HLB value11.5Guoli Chemical Product Database
Cloud point50~60°CGuoli Chemical Product Database
Acid value≤1.0 mg KOH/gGuoli Chemical Product Database
Saponification value≤2.0 mg KOH/gGuoli Chemical Product Database
Hydroxyl value65-75 mg KOH/gGuoli Chemical Product Database
Iodine valueApproximately 90 g I₂/100gGuoli Chemical Product Database
Moisture content≤1.0%Guoli Chemical Product Database
Density (25°C)Approximately 1.05 g/cm³Guoli Chemical Product Database
Kinematic viscosity (25°C)Approximately 800 mm²/sGuoli Chemical Product Database
Low shear viscosity (25°C)Approximately 1000 mPa·sGuoli Chemical Product Database
Refractive index (25°C)1.490-1.500Guoli Chemical Product Database
Surface tension (1% aqueous solution, 25°C)Approximately 32 mN/mGuoli Chemical Product Database
Critical micelle concentration (CMC)Approximately 0.02-0.05 g/LGuoli Chemical Product Database
Melting point<-10°CGuoli Chemical Product Database
Flash point>150°CGuoli Chemical Product Database
Penetration power (standard canvas method)>300 sGuoli Chemical Product Database
Foam performanceLow foamingGuoli Chemical Product Database
HygroscopicityLowGuoli Chemical Product Database
Chemical stabilityStable, resistant to acids, alkalis, and electrolytesGuoli Chemical Product Database
Heavy metal content≤10 mg/kgGuoli Chemical Product Database
Arsenic content≤2 mg/kgGuoli Chemical Product Database
UnsaturationApproximately 3.5 mol/kgGuoli Chemical Product Database
Free alcohol content≤3%Guoli Chemical Product Database
Packaging specifications50kg plastic drum / 200kg plastic drum / IBC tote tankGuoli Chemical Product Database

Application suggestions

The HLB value of this product is approximately 11.5, making it an oil-in-water (O/W) emulsifier, particularly suitable for medium polarity oil phase systems. In pesticide formulations, it is recommended for preparing emulsifiable concentrates, emulsion concentrates, and microemulsions, with a recommended addition amount of 3%~10% of the total formula weight. In emulsion polymerization, it is used as an emulsifier to effectively control the latex particle size and distribution, with a recommended dosage of 1%~4% of the monomer weight. Due to the different EO addition numbers, 600-2 and 600-1 can be combined to obtain a wider HLB coverage range and synergistic effects.

When used in industrial cleaning formulations, due to its low foaming characteristics and excellent acid and alkali resistance, it is particularly suitable for formulating metal degreasers and hard surface cleaners, with a recommended addition amount of 5%~15%. When used as a leveling agent or penetrating agent in textile auxiliaries, the recommended concentration in the working solution is 0.5~3 g/L.

Precautions

  • The product is classified under GHS as skin irritant (Category 2) and eye irritant (Category 2). Nitrile rubber protective gloves and chemical safety goggles must be worn during operation.
  • Solidification or increased viscosity may occur at low temperatures; this is a normal physical phenomenon. It can be restored by warming up to 5~35°C and stirring evenly before use, without affecting product quality.
  • It is recommended to store in a cool, dry, and well-ventilated place, away from strong oxidizing agents. Keep the container sealed and follow the first-in, first-out principle.
  • Avoid contact with skin and eyes. In case of contact, rinse immediately with plenty of water for at least 15 minutes. Seek medical attention if severe.
  • Although the flash point is above 150°C, combustible vapors may still be generated at high temperatures. Good ventilation should be maintained in the workplace.