Question

PEG600DO, main components of Polyethylene Glycol 600 Dioleate?

Answer
2026-05-17 官方文档 PEG600DO,聚乙二醇600双油酸酯

The main component of PEG600DO is the diester product formed by the esterification reaction of Polyethylene Glycol 600 with oleic acid, with a diester content ≥95% and an effective active substance content ≥99%.

Detailed Description

The core component of PEG600DO (Polyethylene Glycol 600 Dioleate) is Polyethylene Glycol 600 Dioleate, with the molecular formula C36H66O4(C2H4O)n (where n≈13) and an average molecular weight of approximately 1100. This product is formed by the esterification reaction of the hydroxyl groups at both ends of the Polyethylene Glycol 600 (PEG-600) molecular chain with two molecules of oleic acid (C18 unsaturated fatty acid), belonging to nonionic gemini surfactants.

The main structural composition of the product is: a hydrophilic polyoxyethylene chain segment (containing approximately 13 ethylene oxide units on average) serving as the backbone, with a lipophilic oleic acid group (C17H33COO-) attached at each end. This A-B-A type block molecular structure endows it with unique amphiphilic properties—it can form stable molecular oriented arrangements at the oil/water interface and can be well compounded with other anionic, cationic, and nonionic surfactant systems.

According to actual data from the Guoli Chemical database, besides the main component diester, the product may contain small amounts of by-products: monoester content ≤5%, free alcohol ≤3%, moisture ≤1.0%, acid value of finished product ≤2 mgKOH/g, saponification value in the range of 90~110 mgKOH/g. The product appears as a light yellow to yellow liquid, CAS number 9004-96-0.

Technical Parameters

Parameter ItemIndicator
Diester Content≥95%
Monoester Content≤5%
Effective Active Substance Content≥99%
Free Alcohol≤3%
Acid Value≤2 mgKOH/g
Saponification Value90~110 mgKOH/g
Hydroxyl Value≤10 mgKOH/g
Iodine Value40~60 gI₂/100g
Moisture≤1.0%
HLB Value10~11
Molecular WeightApproximately 1100
Molecular FormulaC36H66O4(C2H4O)n, n≈13
AppearanceLight yellow to yellow liquid

Application Recommendations

Due to its high diester content and moderate HLB value in the range of 10~11, this product can balance emulsification efficiency and emulsion stability in emulsified formulations. It is recommended to be added at 2%~8% in cosmetic creams/lotions, diluted to 5%~15% working solution in metalworking cutting fluids, and used as an emulsifier in pesticide emulsifiable concentrates at 5%~15% of the total formulation. The specific dosage should be optimized through experiments based on the formulation system and target performance.

Since this product is a nonionic surfactant, its emulsification performance is less affected by water hardness and pH. It is dispersible in water and soluble in organic solvents such as ethanol and acetone, offering strong formulation adaptability.

Precautions

  • The cloud point of this product is approximately 55~65°C. If the operating temperature exceeds the cloud point, phase separation may occur. It is recommended to use it below the cloud point to ensure emulsification effect.
  • The diester content ≥95% is a core quality indicator of the product. When purchasing, attention should be paid to verify this indicator to ensure formulation stability between batches.
  • Storage temperature is recommended at 5~40°C, away from strong oxidizers, avoiding high temperature or direct sunlight to prevent hydrolysis or oxidative degradation of the diester structure.