Question

What is Polyether F-68? What are its main uses?

Answer
2026-06-06 官方文档 聚醚F-68

Polyether F-68 (Poloxamer 188) is a nonionic block polyether surfactant with a high HLB value. Its core applications are concentrated in three high-safety areas: pharmaceutical injection emulsification, biological cell culture protection, and mild emulsification in personal care products.

Detailed Description

Polyether F-68, with the full chemical name α-hydro-ω-hydroxypoly(oxyethylene)poly(oxypropylene)poly(oxyethylene) block copolymer, CAS number 9003-11-6, is a classic nonionic surfactant produced by Guoli Chemical. Its molecular weight ranges from 7680 to 9510, and it appears as a white to slightly yellow waxy solid. This product has many aliases in the industry, including Poloxamer 188, Lutrol F68, Kolliphor P 188, Synperonic PE/F68, and Pluronic F-68, all referring to the same substance.

In terms of technical characteristics, Polyether F-68 has extremely high hydrophilicity, with an HLB value of 29, making it one of the most hydrophilic emulsifiers currently available. The cloud point of its 1% aqueous solution exceeds 100°C, and its surface tension is approximately 43 mN/m (0.1% aqueous solution, 25°C), with a critical micelle concentration (CMC) of about 0.5 g/L. Additionally, the product has an active content of ≥99.0% and exhibits good acid-base tolerance and hard water compatibility, maintaining stable interfacial activity under harsh conditions.

Polyether F-68 is widely used in high-standard pharmaceutical, biotechnology, and personal care fields. Its core mechanism lies in the unique block structure that forms a stable hydrophilic interfacial film, serving both as a solubilizing carrier for poorly soluble drugs and as a physical shear protection agent in cell culture—a dual function rarely achieved by ordinary surfactants.

Key Technical Parameters

ParameterValue/Description
CAS Number9003-11-6
AppearanceWhite to slightly yellow waxy solid
Melting Point52~57°C
Ionic TypeNonionic
HLB Value29
Cloud Point (1% aqueous solution)>100°C
Critical Micelle Concentration (CMC)Approx. 0.5 g/L (25°C)
Surface Tension (0.1%)Approx. 43 mN/m (25°C)
Active Content≥99.0%
pH (1% aqueous solution)5.0~8.0
Hydroxyl Value9~12 mg KOH/g
Acid Value≤0.5 mg KOH/g
Moisture Content≤0.5%
SolubilityReadily soluble in water

Applications and Usage Recommendations

1. Pharmaceutical Industry

As a nonionic surfactant, Polyether F-68 is mainly used as an emulsifier, solubilizer, and stabilizer in liquid preparations such as intravenous injectable emulsions, oral solutions, and eye drops. It can significantly enhance the bioavailability of poorly soluble drugs and ensure the stability of formulations during storage. It is also used as a hydrophilic base for suppositories. This is the application direction with the highest safety standards for this product.

2. Biotechnology and Cell Culture

In cell culture processes, Polyether F-68 is added directly to the culture medium as a shear protection agent, effectively protecting sensitive cells from fluid mechanical damage during agitation and aeration, thereby improving cell viability and product expression levels. According to data from the Guoli Chemical database, the recommended usage concentration is 0.5 to 3 g/L.

3. Personal Care and Cosmetics

Used in formulations such as creams, lotions, shampoos, and body washes as a mild nonionic emulsifier, dispersant, and foam stabilizer. It can effectively improve the spreadability, skin feel, and low-temperature stability of the product, making it especially suitable for formulations for sensitive skin care.

4. Industrial Auxiliaries

Used as a high-performance additive in lubricants, low-foam defoamers, mold release agents, and dispersants for coatings and inks, improving processing performance and surface finish of products.

Precautions

  • GHS Warning: According to database safety information, this product is classified under GHS as Skin irritation (Category 2), Serious eye irritation (Category 2A), and Respiratory irritation (Category 3). The signal word is "Warning," with hazard codes H315, H319, and H335. Nitrile rubber protective gloves, sealed goggles, and dust masks should be worn during handling.
  • Storage Conditions: Keep containers tightly closed and store in a cool, dry place below 25°C, away from strong oxidizers and open flames, and avoid prolonged exposure to humid environments.
  • Hygroscopicity: This product has certain hygroscopicity. After use, the packaging must be immediately resealed to prevent caking or changes in activity.
  • Waste and Emissions: Waste must not be discharged into sewers or surface waters; it must be incinerated or disposed of harmlessly by qualified agencies.