Question

How to use Polyether L-63? What is the recommended dosage?

Answer
2026-06-06 官方文档 聚醚L-63

Usage methods and recommended dosage of Polyether L-63 vary depending on the specific application formulation system; the database does not include standard dosage data for all fields.

Detailed Explanation

Polyether L-63 (CAS No.: 9003-11-6) is a nonionic polyether polyol, with its core use as a polyol component in polyurethane products participating in chemical reactions. In polyurethane systems, it reacts with isocyanates (such as MDI, TDI) to form polyurethane molecular chains, rather than being a simple physical addition. Therefore, its "dosage" needs to be calculated within the entire formulation system, primarily based on the hydroxyl value (54~58 mgKOH/g) of Polyether L-63 and the isocyanate index, while also considering the types and amounts of other polyols, blowing agents, and catalysts for comprehensive adjustment.

When used as a surfactant (emulsifying, wetting, dispersing, etc.), Polyether L-63 is typically added as an additive. Based on its HLB value of 7-8, it is suitable for water-in-oil (W/O) or partial oil-in-water (O/W) emulsion systems. The recommended dosage should be determined through gradient trials in sample testing, not by rigidly applying a fixed proportion.

Application Recommendations

Polyurethane High-Resilience Flexible Foam (Cold Cure Molding): Used as the main polyol component or in combination with other polyols, its proportion in the polyol mixture is typically 60~100 parts (based on 100 parts total polyols). It requires appropriate water (blowing agent), amine and tin catalysts, and isocyanate. Specific dosage must be determined through formulation calculation; starting with 75 parts in trials for optimization is recommended.

Self-Skinning Foam / Semi-Rigid Foam / Microcellular Elastomer: L-63 usage in the polyol component generally ranges from 30~80 parts, adjusted based on the target product's hardness, resilience, and skin quality requirements. Microcellular elastomers (e.g., shoe soles) have higher demands on system compatibility and reaction speed control; it is recommended to first conduct small-scale tests to confirm compatibility with isocyanate prepolymers.

Polyurethane Adhesives and Coatings: As the main or modified polyol in the A component (hydroxyl component) of two-component systems, its proportion can range from 20~80%. When used to enhance flexibility, start with 15-30% of the total A component; if used as the main polyol, strictly calculate the dosage according to the NCO/OH molar ratio of 1.0~1.05.

Surfactant Applications (Emulsifying/Dispersing/Wetting): When Polyether L-63 is only utilized for its surfactant function (not as the main reactant), the recommended dosage is generally 0.5%~5% of the total system weight. For example, 2~5% for metalworking fluid emulsifiers, 0.5~2% for textile leveling agents or dispersants (based on working fluid). Optimal dosage should be confirmed through gradient trials due to variations in water quality, temperature, and other components.

Technical Parameters

Parameter Typical Value
AppearanceColorless to slightly yellow transparent viscous liquid
Ion TypeNonionic
Molecular WeightApprox. 3000
Hydroxyl Value54~58 mgKOH/g
HLB Value7~8
Acid Value≤0.05 mgKOH/g
Water Content≤0.05%
pH Value (1% Aqueous Solution)5.0~7.0
Density (25°C)Approx. 1.03 g/cm³
Kinematic Viscosity (25°C)Approx. 400 mm²/s
Cloud Point (1% Aqueous Solution)Approx. 34°C
Flash Point (Closed Cup)>220°C
Active Content≥99%

(Data source: Guoli Chemical Product Database)

Precautions

  • Prioritize Formulation Calculation: In polyurethane applications, dosage must be precisely calculated based on hydroxyl value and preset isocyanate index; do not add arbitrarily based on experience, as this may lead to abnormal foaming or incomplete curing.
  • Moisture Control: Polyurethane reactions are extremely sensitive to moisture. Polyether L-63 has very low water content (≤0.05%). Keep the container lid sealed before use, and use promptly after opening to avoid moisture absorption affecting performance.
  • Temperature Management: Viscosity increases at low temperatures in winter; it is recommended to use at 15~30°C. If freezing occurs (pour point approx. -30°C), stir evenly after returning to room temperature; quality is not affected.
  • Personal Protection: Wear chemical protective gloves and safety goggles during operation to avoid splashing into eyes. If accidentally splashed into eyes, rinse with plenty of water and seek medical attention.
  • Incompatible Substances: Keep away from strong oxidizers, strong acids to prevent deterioration.