Question

How to use Tween T-80?

Answer
2026-05-17 官方文档 吐温T-80

Tween T-80 is a versatile high-HLB non-ionic emulsifier and solubilizer, and its usage method varies by application scenario, with the core principle being to master the correct addition sequence, dosage ratio, and homogenization process.

Detailed Explanation

Tween T-80 (Polyoxyethylene (20) Sorbitan Monooleate) has an HLB value of 15, making it a hydrophilic O/W (oil-in-water) emulsifier. It is liquid at room temperature and readily soluble in water and various organic solvents. The general usage principle is to precisely control the concentration and adopt appropriate dispersion and emulsification processes based on the final product system type. Due to its high viscosity (kinematic viscosity of approximately 425 mm²/s at 40°C), it may be viscous at low temperatures. It is recommended to preheat it to 25-30°C before use to facilitate pouring and mixing, or first pre-disperse it with a small amount of warm water to activate it before adding to the main system.

In emulsification applications, when preparing oil-in-water emulsions, Tween T-80 is typically dissolved in the water phase, and the oil phase is slowly added under rapid stirring (e.g., using a homogenizer or colloid mill). The recommended dosage is 0.5%-5% of the total system weight. To enhance long-term emulsion stability, it is often combined with low-HLB emulsifiers (such as the Span series) to form a composite emulsification system. In solubilization applications, such as solubilizing poorly soluble flavors, fat-soluble vitamins, or essential oils into water-based formulations, the classic method is to pre-mix Tween T-80 with the substance to be solubilized in a ratio of 1:1 to 3:1 until uniformly transparent, then slowly add this mixture into water under gentle stirring to form a clear, transparent micellar solution.

Technical Parameters

Parameter ItemTypical ValueImpact on Usage Method
AppearanceLight yellow to amber liquidBecomes nearly colorless when dissolved in water, does not affect the color system of the finished product
HLB Value15.0High HLB value determines its priority use as O/W emulsifier and solubilizer
Active Content≥97%High effective concentration; dosage calculation in formulations should be based on actual active content
pH Value (1% aqueous solution)5.0 - 7.0Weakly acidic to neutral, beneficial for protecting pH-sensitive components
Kinematic Viscosity (40°C)Approx. 425 mm²/sHigh viscosity at room temperature; preheating or dilution recommended for handling
Cloud Point (1% aqueous solution)Approx. 93°CRemains clear in high-temperature process water; good thermal stability
Critical Micelle Concentration (CMC)1.3×10⁻⁵ mol/LVery low CMC value means micelle formation with minimal amount; high solubilization efficiency
Saponification Value45~55Mild; a safety reference indicator for food and pharmaceutical grade applications
Water Content≤3.0%Low moisture content, helpful for controlling overall water activity of the formulation
Flash Point>149°CKeep away from open flames during use; control heating below this temperature

Application Suggestions

  • As an O/W emulsifier: Add Tween T-80 to the water phase and preheat. Slowly add the oil phase under homogenization (3000-10000 rpm). Combining with low-HLB emulsifiers (such as Span-80) can further optimize emulsion droplet size and long-term stability. Recommended total emulsifier dosage is 5%-15% of the oil phase weight.
  • As a solubilizer: Mix Tween T-80 with the substance to be solubilized (e.g., essential oils, fragrances, fat-soluble vitamins) at a ratio of 1:1 to 3:1 at room temperature with stirring until homogeneous and transparent. Then slowly add this mixture into water under low-speed stirring to spontaneously form a transparent microemulsion.
  • As a pigment wetting dispersant: First dissolve Tween T-80 (recommended dosage of 0.5%-3% of pigment dry weight) in water or base material, then add pigment/filler powder. After sand milling or ball milling, a homogeneous paste with high hiding power and no flocculation can be obtained.
  • As a pesticide emulsifier: When preparing emulsifiable concentrates (ECs), Tween T-80 is often combined with anionic emulsifiers (such as calcium dodecylbenzenesulfonate) at a dosage of 5%-20% of the total EC weight to ensure spontaneous emulsification and solution stability upon dilution.
  • As an industrial cleaning aid: Add 0.1%-1.0% Tween T-80 directly into the final cleaning formula to effectively solubilize fragrances and hydrophobic oils while maintaining product transparency and flowability at low temperatures.

Precautions

  • The product is low-foaming; it is not suitable for use as the primary surfactant alone in applications that rely on foam (such as some foaming cleaning products).
  • It may undergo hydrolysis under prolonged exposure to strong acids (pH<4) and strong bases (pH>10). The system pH should be stabilized within 4.0-9.0 during formulation.
  • Although generally recognized as safe (GRAS), when used in food, pharmaceuticals, and injectables, specific grades meeting corresponding pharmacopoeia standards (such as the Chinese Pharmacopoeia injection grade) must be chosen.
  • The product is hygroscopic. After opening, unused portions must be immediately sealed under nitrogen to prevent moisture absorption and bacterial contamination.