Question

What is 600P-85% tristyrylphenol polyoxyethylene ether phosphate ester? What are its main uses?

600P-85% tristyrylphenol polyoxyethylene ether phosphate ester is a high-performance anionic surfactant modified by phosphation on the backbone of tristyrylphenol polyoxyethylene ether. It is widely used in seven major fields: pesticide formulations, textile printing and dyeing, metalworking fluids, industrial cleaning, water-based coatings, emulsion polymerization, and oilfield chemicals.

Detailed Description

600P-85% (also known as emulsifier 600P, 600# phosphate ester) is an anionic surfactant with high active matter content (≥85%) produced by Guoli Chemical. This product uses tristyrylphenol polyoxyethylene ether as the backbone, modified by phosphation, possessing dual characteristics of both nonionic and anionic surfactants, exhibiting excellent interfacial control capabilities in complex systems.

Its core advantages lie in: the synergistic effect of the unique multi-aromatic ring lipophilic backbone and polyoxyethylene chain provides excellent emulsification and dispersion capabilities for various oil phases and active substances; the phosphate ester group endows the product with outstanding acid-alkali resistance and hard water tolerance, maintaining stable activity in high-salt and high-electrolyte systems; it also exhibits excellent wetting and spreading properties, low-foaming and foam-suppressing characteristics, and broad formulation compatibility, allowing good compounding with nonionic, anionic, cationic, and amphoteric surfactants.

This product is of low toxicity (rat oral LD50 > 2000 mg/kg), appears as a light yellow to yellow high-viscosity liquid, readily soluble in water and organic solvents, and poses a low risk to human health under normal industrial use conditions. However, it should be noted that this substance is not readily biodegradable, and waste disposal should comply with local environmental regulations.

Technical Parameters

Parameter ItemTechnical IndexParameter ItemTechnical Index
AppearanceLight yellow to yellow liquidIonic TypeAnionic
Active Matter Content≥85%HLB Value12.5
Moisture≤0.5%Density~1.10 g/cm³
pH Value (1% Aqueous Solution)2.0~3.5pH Value (5% Aqueous Solution)2.0~4.0
Acid Value70~110 mgKOH/gMonoester Content40%~60%
Diester Content20%~40%Combined Phosphorus (as P₂O₅)4%~8%
Free Phosphoric Acid (as H₃PO₄)≤0.5%Free Alcohol≤3%
Surface Tension (1% Aqueous Solution)30~35 mN/mCritical Micelle Concentration0.01%~0.05%
Kinematic Viscosity (25°C)2000~5000 mm²/sFlash Point>150°C
Foaming CharacteristicsLow to medium foamingCloud PointNone (anionic type generally has no cloud point)
Heavy Metals (as Pb)≤10 mg/kgArsenic Content≤2 mg/kg
Chemical StabilityStable under normal conditions, avoid strong alkalisPackaging Specifications50kg/200kg plastic drum, IBC tote

Application Recommendations

Pesticide Formulations: Suitable for emulsifiable concentrates (EC), emulsions in water (EW), microemulsions (ME), suspension concentrates (SC), and oil-based suspension concentrates (OD), as a highly effective emulsifier and dispersant. The recommended dosage should be determined through gradient tests based on the formulation type and oil phase properties, usually added during the acid or alkali adjustment stage and stirred thoroughly.

Textile Printing and Dyeing: Used as a core component of high-temperature leveling agents, scouring agents, and dispersants, helping dyes to evenly dye, preventing color spots and streaks, and improving fabric hand feel and color fastness.

Metalworking and Industrial Cleaning: Provides excellent emulsification and anti-rust properties in metal cutting, wire drawing, and other processing fluids, recommended at 5%~15% of the total formulation. In hard surface cleaning formulations, it effectively removes oil stains while offering low foaming and anti-corrosion performance.

Water-Based Coatings and Inks: Acts as an efficient wetting and dispersing agent for pigments and fillers, recommended at 2%~8% of the pigment weight, effectively preventing floating color, flooding, and pigment sedimentation, improving the storage stability and color development of pigment pastes.

Emulsion Polymerization: Provides fine and stable micelles for emulsion polymerization systems such as vinyl acetate and acrylates, controlling particle size distribution and improving the overall performance of polymer emulsions. In the oilfield sector, it can be used in drilling fluids and enhanced oil recovery operations, withstanding high temperature and high salt downhole environments.

Precautions

  • Safety Protection: Wear chemical safety goggles, chemical-resistant protective gloves, and protective clothing during operation, avoiding direct contact with eyes and skin. Maintain good ventilation in the work area.
  • Storage Conditions: Store in a cool, dry, well-ventilated warehouse, recommended temperature 5°C~40°C, away from heat sources, sparks, and open flames. Use corrosion-resistant sealed containers for storage, and keep away from strong oxidizers, strong alkalis, and strong acids.
  • Emergency Treatment: In case of skin contact, immediately wash with plenty of water and soap for at least 15 minutes; for eye contact, rinse with flowing water for at least 15 minutes and seek medical attention immediately; if ingested, do not induce vomiting, seek immediate medical help.
  • Environmental Requirements: This product is not readily biodegradable, and leakage must not be directly discharged into sewers, soil, or any water bodies. Waste disposal should comply with local environmental regulations.
  • Usage Tips: After opening, use up as soon as possible; if not fully used, reseal and store properly. It is recommended to determine the optimal addition ratio through gradient tests and optimize the synergistic proportion with other auxiliaries.