Question

What are the physicochemical technical parameters of PEG400DO, polyethylene glycol 400 dioleate?

Answer
2026-06-06 官方文档 PEG400DO,聚乙二醇400双油酸酯

PEG400DO physicochemical parameters are comprehensive, with key indicators including HLB value 8.5, diester content ≥90%, molecular weight 900~1000, making it a typical lipophilic nonionic emulsifier

Detailed description

PEG400DO (polyethylene glycol 400 dioleate, CAS: 9004-96-0) is a diester-type nonionic surfactant formed by esterification of polyethylene glycol 400 with oleic acid. Its molecular formula can be represented as C17H33COO(CH2CH2O)nOCC17H33 (n≈8). The product appears as a light yellow to amber liquid, with an effective content ≥99%, belonging to high-purity diester products, and is chemically stable under normal storage conditions.

The HLB value of this product is approximately 8.5, making it a lipophilic emulsifier that can be dispersed in water and soluble in organic solvents such as ethanol and acetone. The ester bonds in its molecular structure are prone to hydrolysis under strong alkaline conditions, so formulation design should avoid long-term coexistence with strong alkaline components. The product is a low-foaming surfactant, which can reduce foam interference in industrial applications and is suitable for processes requiring rapid defoaming.

With excellent emulsifying, dispersing, and wetting properties imparted by its diester structure, PEG400DO is widely used in textile oils, metalworking fluids, industrial lubricants, personal care products, and agricultural chemical formulations. The product has low ecotoxicity and is easily biodegradable. During operation, relevant GHS protective requirements should be followed to avoid direct skin and eye contact.

Technical parameters

Parameter nameSpecification/valueRemarks
CAS number9004-96-0(Source: Guoli Chemical Product Database)
AppearanceLight yellow to amber liquid(Source: Guoli Chemical Product Database)
Ionic typeNonionic(Source: Guoli Chemical Product Database)
Molecular weight900~1000(Source: Guoli Chemical Product Database)
Effective content≥99%(Source: Guoli Chemical Product Database)
Diester content≥90%(Source: Guoli Chemical Product Database)
Monoester content≤5%(Source: Guoli Chemical Product Database)
Free alcohol≤2%(Source: Guoli Chemical Product Database)
HLB value8.5(Source: Guoli Chemical Product Database)
Cloud point (1% aqueous solution)40~50℃(Source: Guoli Chemical Product Database)
pH value (1% aqueous solution)5.0~7.5(Source: Guoli Chemical Product Database)
pH value (5% aqueous solution)4.5~7.5(Source: Guoli Chemical Product Database)
Acid value≤5.0 mg KOH/g(Source: Guoli Chemical Product Database)
Saponification value116~126 mg KOH/g(Source: Guoli Chemical Product Database)
Hydroxyl value≤15 mg KOH/g(Source: Guoli Chemical Product Database)
Iodine value55~65 g I₂/100g(Source: Guoli Chemical Product Database)
Moisture content≤0.5%(Source: Guoli Chemical Product Database)
Density1.11~1.13 g/cm³(Source: Guoli Chemical Product Database)
Kinematic viscosity (25℃)100~200 mm²/s(Source: Guoli Chemical Product Database)
Low shear viscosityApprox. 100~200 mPa·s(Source: Guoli Chemical Product Database)
Refractive index1.466~1.468(Source: Guoli Chemical Product Database)
Flash point>200℃(Source: Guoli Chemical Product Database)
Surface tension (0.1%, 25℃)Approx. 30 mN/m(Source: Guoli Chemical Product Database)
Critical micelle concentration (CMC)Approx. 1×10⁻⁴ mol/L(Source: Guoli Chemical Product Database)
SolubilityDispersible in water, soluble in organic solvents such as ethanol and acetone(Source: Guoli Chemical Product Database)
Foaming propertyLow foaming(Source: Guoli Chemical Product Database)
Alkali resistanceNot alkali resistant, ester bonds