Question

Is PEG400DO (PEG 400 Dioleate) harmful to human health? Does it have an environmental impact?

Answer
2026-06-06 官方文档 PEG400DO,聚乙二醇400双油酸酯

PEG400DO (PEG 400 Dioleate) is a low-toxicity nonionic surfactant that poses low hazard to human health under normal use conditions, but attention should be paid to its irritation to skin, eyes and respiratory tract; its overall environmental impact is relatively small due to its ready biodegradability.

Detailed Description

PEG400DO (PEG 400 Dioleate) is classified as a low-toxicity substance in toxicology. Its acute oral toxicity is extremely low, with a rat oral LD50 greater than 5000 mg/kg, and under exposure levels in daily industrial and consumer product formulations, it does not pose a systemic toxicity risk. However, its local irritation to humans cannot be ignored — direct contact may cause skin irritation (H315), splash into eyes causes serious eye irritation (H319), and inhalation of vapor or mist may cause respiratory tract irritation (H335). These hazard categories are GHS Category 2 or Category 3, representing moderate reversible irritation, not corrosive or permanent damage.

In terms of environment, the ecotoxicity level of PEG400DO is relatively mild. Studies have shown that it may have some harmful effects on aquatic organisms, but because the product is readily biodegradable, it does not persist or accumulate in the natural environment for a long time. Microorganisms in wastewater treatment systems can effectively decompose it, without causing continuous harm to the aquatic ecosystem. Overall, as long as emission and treatment are carried out in accordance with regulations, its environmental impact is controllable and minimal.

Technical Parameters

Safety IndicatorParameter
GHS Skin Irritation ClassificationCategory 2 (Causes skin irritation)
GHS Eye Irritation ClassificationCategory 2 (Causes serious eye irritation)
GHS Specific Target Organ Toxicity (Single Exposure)Category 3 (Respiratory tract irritation)
Acute Oral Toxicity (Rat)LD50 > 5000 mg/kg
BiodegradabilityReadily biodegradable
Aquatic EcotoxicityMay cause harmful effects to aquatic organisms
Overall Toxicity GradeLow-toxicity substance

Application Suggestions

Based on its safety profile, PEG400DO can be safely used in personal care products (facial cleansers, body washes, makeup removers, etc.), textile oils, metalworking fluids, agrochemical formulations, and industrial lubricants. The typical addition level in formulations is between 1% and 10%, within which the skin irritation of the finished product is greatly reduced. As a nonionic surfactant, its mild nature makes it particularly suitable for daily chemical product formulations requiring high skin compatibility.

Precautions

  • Personal protection: Wear protective gloves, protective clothing, eye protection/face shield (P280) during operation to avoid direct contact with skin and eyes.
  • Ventilation requirements: Avoid inhalation of vapor, mist or spray. Keep the workplace well ventilated (P261).
  • Emergency measures: If in eyes, rinse cautiously with water for several minutes. Remove contact lenses if present and easy to do, continue rinsing (P305+P351+P338). If eye irritation persists, seek medical advice/attention (P337+P313).
  • Post-work cleaning: Wash hands and exposed areas thoroughly after handling (P264).
  • Environmental management: Although the product is readily biodegradable, avoid direct discharge into natural waters without treatment. It is recommended to treat through a standard wastewater treatment system before discharge.