Peregal O-50/100

Peregal O-50/100

Peregal O-50/100 is a high polymerization degree fatty alcohol polyoxyethylene ether nonionic surfactant, used as textile dyeing leveling agent, glass fiber emulsifier and industrial detergent.

CAS No. 68439-49-6
Packaging 20kg woven bag
Updated 2026-06-11
Reference Price: 10981.75 ¥/ton
Updated: 2026-06-11

1. Product Overview

Peregal O-50/100 belongs to the fatty alcohol polyoxyethylene ether (AEO) series of nonionic surfactants, chemically named polyethylene glycol fatty alcohol ether. It is produced by addition polymerization of natural fatty alcohol (C16-C18) with ethylene oxide (EO). When the EO addition number is approximately 50, it corresponds to Peregal O-50; when approximately 100, it corresponds to Peregal O-100.

Peregal O-50 is a white to slightly yellow waxy solid, readily soluble in hot water and dispersible in cold water. Peregal O-100 is a white to slightly yellow flake or granular solid, readily soluble in water forming a clear solution. Both are non-toxic, non-irritating and exhibit good biodegradability. They are high-performance O/W nonionic emulsifiers, dispersants and leveling agents, widely used in textile dyeing, household chemicals, pesticide formulations and emulsion polymerization.

Their core advantage lies in the extremely long polyoxyethylene chains which impart very high hydrophilicity and outstanding steric stabilization, producing emulsions and dispersions with fine particle size and excellent stability, particularly suitable for industrial formulations requiring electrolyte resistance, high-temperature tolerance and long-term stability.

2. Performance Features

  1. Outstanding emulsifying and stabilizing power: The ultra-long EO chains provide strong steric hindrance effects, giving extremely strong emulsifying power for mineral oils, vegetable oils, fatty acids and waxes. The resulting emulsions have fine particle size and outstanding long-term stability, especially suitable for systems requiring extended storage or high-temperature transport.
  2. Efficient dispersing and leveling: Effectively adsorbs onto solid particle surfaces, preventing agglomeration and sedimentation. When applied to dye and pigment processing, significantly improves levelness and color fastness while reducing spotting and streaking.
  3. Outstanding electrolyte and hard water resistance: Maintains stable performance across a wide pH range and in high-concentration salt and hard water environments without decomposition, salting-out or failure, outperforming most conventional nonionic surfactants.
  4. Extremely low foaming: Compared with low EO-number AEO products, Peregal O-50/100 has extremely low foaming, virtually foam-free, especially suitable for circulation pumping, spray cleaning and other industrial operations where foam must be strictly controlled.
  5. Excellent compatibility and synergy: Good compatibility with anionic, cationic and other nonionic surfactants, producing synergistic effects through mixed micelle formation and improving overall formulation cost-effectiveness.
  6. Safe and eco-friendly: Non-toxic, non-irritating to skin, with excellent biodegradability, meeting modern green chemistry and sustainable development requirements. Safe for use in consumer product formulations with indirect human contact.

3. Applications

  • Textile Dyeing: Used as a high-temperature high-pressure leveling agent, dispersant, scouring agent and soaping agent for various fibers, especially suitable for polyester and blended fabric high-temperature dyeing.
  • Emulsion Polymerization: Serves as an O/W emulsifier and stabilizer for vinyl acetate, acrylate and other systems, producing polymer emulsions with uniform particle size and excellent stability.
  • Pesticide Formulations: Used in water emulsions (EW), microemulsions (ME), suspension concentrates (SC) and other eco-friendly formulation types, improving wetting and spreading on target surfaces.
  • Industrial Cleaning: Used in formulating low-foam metal cleaners and hard surface cleaners, combining outstanding degreasing with anti-rust functionality.
  • Household Chemicals: Applied in textile softeners, various creams and lotions, hair conditioners and other products as an emulsifying and solubilizing component.
  • Other Industries: Used as a high-performance dispersant and stabilizer in papermaking deinking, pigment dispersion, water-based inks and other fields.

4. Usage Instructions

Dissolution Guide: Slowly add the product to hot water at 40-60°C with continuous stirring until completely dissolved, then incorporate into the formulation and mix thoroughly. Peregal O-100 can also be directly dispersed and dissolved in room temperature aqueous solutions. Conduct small-scale trials to determine the optimal addition amount and dissolution conditions for specific processes.

Peregal O-50/100 Applications

With ultra-long polyoxyethylene chains providing extremely high hydrophilicity and steric stabilization, Peregal O-50/100 offers outstanding performance in demanding applications:

  • Textile dyeing: As a high-temperature high-pressure leveling agent and dispersant for polyester and blended fabric dyeing at 130°C. Also used as a soaping agent in reactive dye post-treatment at 80-95°C. Dosage: 0.1%-0.5% in dyebath.
  • Emulsion polymerization: As an O/W emulsifier and stabilizer for vinyl acetate, acrylate and styrene-acrylic systems, producing polymer emulsions with fine particle size and excellent mechanical and thermal stability. Dosage: 1%-4% on monomer.
  • Pesticide formulations: In EW, ME and SC eco-friendly formulation types to improve wetting, spreading and emulsion stability. Dosage: 4%-10%.
  • Industrial cleaning: In low-foam metal cleaners and hard surface cleaners, combining excellent degreasing with anti-rust functionality. Dosage: 1%-5%.
  • Heavy-duty cleaning: Peregal O-100 shows outstanding emulsification and detergency against seal oils and mechanical greases in high-temperature, strong-alkaline cleaning systems.

Product Properties

Property Value
CAS No. 68439-49-6
Molecular Formula C16-18H33-37O(C2H4O)nH, n≈50-100
Appearance White to slightly yellow flake or solid (at room temperature)
Ionic Type Nonionic
Avg. Molecular Weight O-50 Approx. 2500, O-100 Approx. 4500
Cloud Point >95
Active Content ≥99
pH Value(1%) 5.0~7.0
pH Value(5%) 5.0~7.0
Iodine Value ≤2
Solubility Readily soluble in water, ethanol, acetone and other organic solvents; insoluble in petroleum ether
Surface Tension 30-35 mN/m (1%aq. soln., 25°C)
CMC ~1×10⁻⁵ mol/L (25℃)
Acid Value ≤1.0
Saponification Value ≤1
Hydroxyl Value O-50: ~18-22, O-100: ~9-11
Moisture ≤1.0
Density ~1.0 g/cm³ (solid)
Kinematic Viscosity ~50-200 mm²/s (65°C, molten state)
Refractive Index ~1.450-1.460 (50°C)
Flash Point >200°C
Hygroscopicity Slightly hygroscopic
Chemical Stability Good chemical stability against acids, alkalis, hard water and oxidizers
Foam Property Low foam
Alkali Resistance Good
Unsaturation ≤0.1 mol/kg
Viscosity O-50: ~60 mPa·s (65°C), O-100: ~150 mPa·s (65°C)
Melting Point O-50~40-45°C, O-100~45-50
Solid Content ≥99
Free Alcohol ≤2%
Heavy Metal ≤10
Arsenic ≤2

Peregal O-50/100 Safety Instructions

Hazard Overview

According to GHS, Peregal O-50/100 (fatty alcohol polyoxyethylene ether) is not classified in any physical hazard category. Health hazards: Acute oral toxicity Category 5 or not classified (LD50>2000 mg/kg, rat); no skin corrosion/irritation (prolonged or high-concentration contact may cause mild irritation); no serious eye damage/irritation (may cause mild discomfort); no respiratory or skin sensitization. Environmental hazards: Low toxicity to aquatic organisms (EC50/LC50>100 mg/L), not classified as acute aquatic hazard. No other known hazards.

Safe Handling Precautions

  1. Operate in a well-ventilated area. Avoid generating and inhaling aerosols or dust.
  2. Avoid contact with eyes and skin. Wash exposed areas thoroughly after handling.
  3. If dust may be generated, use explosion-proof electrical equipment suitable for dust explosion environments. The product itself is non-flammable but may decompose producing irritating fumes at high temperatures.
  4. Do not exceed recommended operating temperatures to prevent thermal decomposition.
  5. Keep containers closed and away from strong oxidizers.
  6. Empty containers may retain product vapor or residue. Maintain warning labels and do not use for food or feed.
  7. Follow general industrial hygiene practices. No eating, drinking or smoking in the work area.

Storage Conditions

  • Store in a cool, dry, well-ventilated dedicated warehouse.
  • Keep container tightly closed. Avoid high temperature and humid environments.
  • Recommended storage temperature not exceeding 40°C. Avoid direct sunlight.
  • Keep away from incompatible substances such as strong oxidizers, strong acids and strong alkalis.
  • Keep away from food, beverages and animal feed storage areas.
  • Regularly inspect packaging integrity to prevent leakage.

Personal Protective Equipment

Respiratory: No special protection typically required. If high concentrations of aerosol or dust are generated, wear particulate filter mask (FFP2/N95).

Hand: Wear chemical protective gloves such as nitrile or neoprene. Wash hands thoroughly after contact.

Eye: Wear chemical safety goggles or face shield to prevent splashing.

Skin and Body: Wear standard work clothing. If heavy splashing may occur, wear impermeable apron or protective clothing.

Emergency Treatment / First Aid

Inhalation: Move victim to fresh air and keep comfortable for breathing. Seek medical attention if symptoms persist.

Skin: Immediately remove contaminated clothing. Flush skin with plenty of water and soap for at least 15 minutes. If irritation or rash occurs, seek medical attention. Wash contaminated clothing before reuse.

Eyes: Rinse immediately with plenty of water or saline solution, keeping eyelids open, for at least 15 minutes. If persistent pain, tearing or redness occurs, seek ophthalmological treatment.

Ingestion: Rinse mouth. Do not induce vomiting. Drink 1-2 glasses of water to dilute. Seek medical attention if discomfort occurs. Show this safety data to the physician.

Most important symptoms/effects: May cause mild gastrointestinal discomfort or diarrhea. No known acute toxic severe effects.

Spill Emergency Treatment

  1. Personal protection: Wear appropriate PPE (gloves, goggles, protective clothing).
  2. Environmental protection: Prevent spill from entering sewers, surface water or groundwater.
  3. Containment and cleanup: Contain and collect spill with inert absorbent material (sand, vermiculite), place in sealed containers for disposal.
  4. Small spills may be flushed with copious water but ensure no water body contamination.
  5. Dispose of waste as chemical waste according to local regulations.

Fire Fighting Measures

Extinguishing media: Use water fog, alcohol-resistant foam, dry powder or carbon dioxide. Avoid direct water jets to prevent splashing and spreading.

Special protection: Firefighters must wear self-contained breathing apparatus and full protective clothing.

Hazardous combustion products: Carbon monoxide, carbon dioxide and possibly irritating or toxic fumes.

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